{"id":"W2405776329","doi":"10.1021/acs.biomac.6b00026","title":"Correlation Between Chain Architecture and Hydration Water Structure in Polysaccharides","year":2016,"lang":"en","type":"article","venue":"Biomacromolecules","topic":"Surfactants and Colloidal Systems","field":"Chemistry","cited_by":93,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Agriculture, Food and Rural Affairs","keywords":"Polysaccharide; Chemistry; Branching (polymer chemistry); Attenuated total reflection; Chemical engineering; Chitosan; Nanomaterials; Materials science; Infrared spectroscopy; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001184829,0.0001044512,0.00006964393,0.0002134133,0.00006612216,0.0001777255,0.00007826634,0.0001186793,0.0007325564],"category_scores_gemma":[0.0004078913,0.0001213581,0.0000744361,0.0001261647,0.0002026534,0.000225546,0.0001059682,0.0001557233,0.00009059119],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006889441,"about_ca_system_score_gemma":0.0000715224,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000423295,"about_ca_topic_score_gemma":0.0007797219,"domain_scores_codex":[0.9999398,0.000009996874,0.000003991657,0.00001429087,0.00001789981,0.00001408745],"domain_scores_gemma":[0.9997028,0.0001254492,0.0000817216,0.00001606579,0.00004086932,0.00003308748],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003518969,0.000005471406,0.003271739,0.00002038267,0.000009212,0.00001931367,0.00002805219,0.0001274057,0.995478,0.00005243533,0.000007138658,0.0009455288],"study_design_scores_gemma":[0.000006209845,0.0002362652,0.1188463,0.000007076085,0.00002940318,0.0001439457,0.00009106332,0.002869669,0.8771049,0.0002246793,0.0004272204,0.00001326536],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986211,0.0002953814,0.000659075,0.00001184679,0.000001527589,0.000002562765,0.00002887714,0.000005281283,0.0003742285],"genre_scores_gemma":[0.9993348,0.0001502766,0.0002817356,0.000007792692,0.000001343779,0.000002365721,0.00004193601,0.000002759291,0.0001770553],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007325564,"threshold_uncertainty_score":0.002450705,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006315658575419512,"score_gpt":0.2039010759587334,"score_spread":0.1975854173833139,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}