{"id":"W2409343170","doi":"10.1002/slct.201600245","title":"Thiacalix[4]arene Derivatives Bearing Imidazole Units: A Ditopic Hard/Soft Receptor for Na + and K + /Ag + with an Allosteric Effect and a Reusable Extractant for Dichromate Anions","year":2016,"lang":"en","type":"article","venue":"ChemistrySelect","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Engineering and Physical Sciences Research Council","keywords":"Imidazole; Chemistry; Titration; Proton NMR; Aqueous solution; Stereochemistry; Medicinal chemistry; Allosteric regulation; Metal ions in aqueous solution; Tetra; Ion; Crystallography; Receptor; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004168795,0.0008897343,0.0008911646,0.0001180951,0.0006990792,0.0003118079,0.0004174214,0.000542504,0.0002449622],"category_scores_gemma":[0.00104278,0.0006953429,0.0001834377,0.0004307302,0.0003178267,0.0005149727,0.0001719085,0.0004059674,0.000005936708],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000223171,"about_ca_system_score_gemma":0.0001861062,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004161731,"about_ca_topic_score_gemma":0.00000465559,"domain_scores_codex":[0.9961737,0.0001010401,0.00068227,0.00149382,0.0004223268,0.001126855],"domain_scores_gemma":[0.9971791,0.0007118734,0.0003399145,0.0008972208,0.0003844523,0.0004874686],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001135624,0.0001455053,0.00153757,0.001587814,0.0003125721,0.00001270628,0.0007302035,0.0003603165,0.9859447,0.0000120112,0.0008023151,0.007418655],"study_design_scores_gemma":[0.004295684,0.0009162006,0.00007525751,0.001113011,0.0002697612,0.0002267555,0.0006253875,0.0379537,0.9446977,0.00008055029,0.008697643,0.00104831],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927291,0.0006485329,0.004412867,0.0002732188,0.00003332275,0.0008775257,0.0003898609,0.0003448092,0.0002907699],"genre_scores_gemma":[0.9929372,0.0002032444,0.003206589,0.0001012435,0.0005955725,0.0007359473,0.0002858957,0.0002237711,0.001710556],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04124697,"threshold_uncertainty_score":0.9995497,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01243530457996449,"score_gpt":0.2299369934278898,"score_spread":0.2175016888479253,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}