{"id":"W2409343170","doi":"10.1002/slct.201600245","title":"Thiacalix[4]arene Derivatives Bearing Imidazole Units: A Ditopic Hard/Soft Receptor for Na + and K + /Ag + with an Allosteric Effect and a Reusable Extractant for Dichromate Anions","year":2016,"lang":"en","type":"article","venue":"ChemistrySelect","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Engineering and Physical Sciences Research Council","keywords":"Imidazole; Chemistry; Titration; Proton NMR; Aqueous solution; Stereochemistry; Medicinal chemistry; Allosteric regulation; Metal ions in aqueous solution; Tetra; Ion; Crystallography; Receptor; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008853326,0.0003395572,0.0002519831,0.00008994784,0.00009091521,0.0002842877,0.000422226,0.0003286388,0.001225454],"category_scores_gemma":[0.00009220115,0.0001358296,0.0001647258,0.00009595406,0.0001791296,0.0002299812,0.0001810198,0.000310374,0.0005076944],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002908089,"about_ca_system_score_gemma":0.0001050769,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003443469,"about_ca_topic_score_gemma":0.000684098,"domain_scores_codex":[0.9999297,0.00001162443,0.000004848214,0.00001746267,0.0000173533,0.00001899469],"domain_scores_gemma":[0.9999123,0.00001255961,0.00002717715,0.00001047275,0.00001154107,0.00002597123],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005567876,0.000008033022,0.00003186726,0.00002154812,0.000002136623,0.00001728512,0.00000478692,0.00003610872,0.9993861,0.00003138864,0.00001964712,0.0003854503],"study_design_scores_gemma":[0.00002030173,0.0002306166,0.0007676576,0.000002775472,0.00001101878,0.00009842853,0.00001374117,0.0008123143,0.9963059,0.000008216733,0.001720504,0.000008442375],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995184,0.0007231415,0.002448503,0.00005777572,0.0000226832,0.00002595156,0.0001387303,0.00008978355,0.001309504],"genre_scores_gemma":[0.9900001,0.0004754377,0.004246874,0.00006050997,0.00001165685,0.00004139744,0.0002423892,0.00001865947,0.004903045],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001225454,"threshold_uncertainty_score":0.004099488,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01243530457996449,"score_gpt":0.2299369934278898,"score_spread":0.2175016888479253,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}