{"id":"W2409913177","doi":"10.1021/acs.inorgchem.5b00634","title":"Synthesis of Carboxylate Cp*Zr(IV) Species: Toward the Formation of Novel Metallocavitands","year":2015,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies; Canada Foundation for Innovation","keywords":"Chemistry; Isostructural; Carboxylate; Diethyl ether; Molecule; Ether; Stereochemistry; Crystallography; Medicinal chemistry; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001054441,0.0003112737,0.0002579046,0.0001659946,0.0001452545,0.000362292,0.0005762917,0.0002817443,0.001250304],"category_scores_gemma":[0.0001866298,0.0001571332,0.000200142,0.0002040346,0.0001528333,0.0002209863,0.0003353888,0.000364644,0.0003544583],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003199726,"about_ca_system_score_gemma":0.0002037385,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006826355,"about_ca_topic_score_gemma":0.000887583,"domain_scores_codex":[0.9999009,0.000009516696,0.000007287058,0.00002793122,0.0000285332,0.00002584362],"domain_scores_gemma":[0.9999506,0.00000469732,0.00001299944,0.000005562376,0.00001141621,0.00001463697],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007135358,0.00001124421,0.00007611133,0.0001398863,0.00001093353,0.00005657629,0.00004346361,0.0001609078,0.995565,0.0007265056,0.0001649723,0.002973003],"study_design_scores_gemma":[0.00003484659,0.0001373036,0.0004145069,0.000005344804,0.00001817758,0.0001384949,0.00001990701,0.0005043886,0.9913116,0.00007964734,0.007327549,0.000008185794],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9722188,0.001892973,0.01529994,0.0001553284,0.00007600903,0.0001290091,0.0004237588,0.0003866444,0.009417532],"genre_scores_gemma":[0.9841898,0.0009222238,0.01001348,0.00006115146,0.00001754937,0.00005033781,0.0003132596,0.00007050785,0.004361494],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001250304,"threshold_uncertainty_score":0.004182637,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04323425790523507,"score_gpt":0.2462853088582429,"score_spread":0.2030510509530078,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}