{"id":"W2410347780","doi":"10.1021/jacs.5b05738","title":"From Molecules to Surfaces: Radical-Based Mechanisms of Si–S and Si–Se Bond Formation on Silicon","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Institute for Nanotechnology; University of Alberta","funders":"Canada Research Chairs","keywords":"Chemistry; Radical; Selenide; Photochemistry; Fourier transform infrared spectroscopy; Sulfide; Reactivity (psychology); Silicon; Organic chemistry; Chemical engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001089217,0.00009682172,0.0002161821,0.00001813398,0.00002125587,0.00001373358,0.0001437605,0.00004243622,0.000004837536],"category_scores_gemma":[0.00007437614,0.00006471675,0.0001668588,0.0001654278,0.00008394058,0.00004068085,0.00002684753,0.0001778295,6.737868e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007684188,"about_ca_system_score_gemma":0.00002419771,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003537175,"about_ca_topic_score_gemma":7.159567e-7,"domain_scores_codex":[0.9993194,0.00002152201,0.0002315934,0.0000646263,0.0002598691,0.0001029566],"domain_scores_gemma":[0.9994555,0.00005827958,0.0001670041,0.0001295758,0.00005777413,0.0001318427],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004235634,0.00001688551,0.0000264342,0.00001026332,0.00004414719,6.18491e-7,0.0002648884,0.008460715,0.9840999,0.00001660841,0.006193345,0.0008238246],"study_design_scores_gemma":[0.0003949298,0.0001237888,0.0002189942,0.00004143916,0.00003687277,0.000006203799,0.000323284,0.01177603,0.985428,0.0009775026,0.0005892281,0.00008378008],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9819124,0.00009665807,0.01726724,0.0005140154,0.00009201547,0.00005437975,0.00001424427,0.00001182082,0.00003721515],"genre_scores_gemma":[0.9859698,0.00001447421,0.01329248,0.0006560386,0.00005036241,9.177545e-7,0.000001691808,0.00001231865,0.000001916681],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005604117,"threshold_uncertainty_score":0.2639073,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008620390343067077,"score_gpt":0.2182667185974569,"score_spread":0.2096463282543898,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}