{"id":"W2410347780","doi":"10.1021/jacs.5b05738","title":"From Molecules to Surfaces: Radical-Based Mechanisms of Si–S and Si–Se Bond Formation on Silicon","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Institute for Nanotechnology; University of Alberta","funders":"Canada Research Chairs","keywords":"Chemistry; Radical; Selenide; Photochemistry; Fourier transform infrared spectroscopy; Sulfide; Reactivity (psychology); Silicon; Organic chemistry; Chemical engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001788166,0.0002588782,0.0001289822,0.0001238269,0.0001147436,0.0002448082,0.0003200736,0.000375923,0.001541687],"category_scores_gemma":[0.0001309253,0.0001084215,0.0002201099,0.00007263901,0.0003054663,0.0003817979,0.0002432639,0.0003713863,0.0003112977],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001401355,"about_ca_system_score_gemma":0.00008062347,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001080766,"about_ca_topic_score_gemma":0.0002210272,"domain_scores_codex":[0.9999071,0.00001510005,0.00000365224,0.00001862421,0.00003146001,0.00002396049],"domain_scores_gemma":[0.9999334,0.00002480469,0.00001599582,0.000009361759,0.00001021496,0.000006263329],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004089984,0.0000159938,0.0002434838,0.0001036224,0.000008073636,0.00008122331,0.0000389761,0.0002474238,0.9960474,0.0006647338,0.00004733185,0.002460866],"study_design_scores_gemma":[0.000007139276,0.0002358713,0.0006378986,0.000003892961,0.000005482446,0.00008954868,0.00003021575,0.0008537754,0.9968267,0.0001727641,0.001133209,0.000003496153],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9891907,0.002015317,0.005955175,0.0001397845,0.00003163217,0.00003603454,0.00005778145,0.00005220857,0.0025214],"genre_scores_gemma":[0.9943848,0.001058063,0.002595497,0.00005255493,0.00001181563,0.0000178335,0.00006681631,0.000007240903,0.001805406],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001541687,"threshold_uncertainty_score":0.005157411,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008620390343067077,"score_gpt":0.2182667185974569,"score_spread":0.2096463282543898,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}