{"id":"W2411670312","doi":"10.1039/c6dt01908k","title":"Synthesis and reactivity of Li and TaMe<sub>3</sub> complexes supported by N,N′-bis(2,6-diisopropylphenyl)-o-phenylenediamido ligands","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto; Government of Ontario","keywords":"Reactivity (psychology); Chemistry; Stereochemistry; Medicinal chemistry; Medicine","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000127177,0.0002603768,0.0001929852,0.0001163728,0.0001422536,0.0003383234,0.000475101,0.0002842213,0.001147655],"category_scores_gemma":[0.0002145978,0.0001988909,0.0001175404,0.0001157335,0.0001537782,0.0001868698,0.0002192967,0.0002917954,0.0005110674],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004362042,"about_ca_system_score_gemma":0.0001468293,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008900037,"about_ca_topic_score_gemma":0.001452508,"domain_scores_codex":[0.9998951,0.000008984716,0.000007843733,0.00002761692,0.00003237724,0.00002799295],"domain_scores_gemma":[0.999893,0.00001590247,0.00003006996,0.00001187677,0.00002107345,0.00002811583],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007348666,0.000009740588,0.0001000809,0.00002355792,0.000004498407,0.00002281009,0.00001846362,0.0001077712,0.9984566,0.000106673,0.00004160625,0.001034649],"study_design_scores_gemma":[0.000007347057,0.00004910528,0.0004250456,0.00000157424,0.00000404629,0.00002289932,0.000005942349,0.0006682166,0.9980519,0.00001034931,0.000750317,0.00000325566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955783,0.0003072246,0.001914349,0.0000384847,0.00001093607,0.00001484233,0.000127725,0.0001109854,0.001897164],"genre_scores_gemma":[0.9951648,0.0001703092,0.002290206,0.00002565254,0.000003642216,0.00001818402,0.0002043198,0.00003420405,0.002088747],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001147655,"threshold_uncertainty_score":0.003839314,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01025668712147457,"score_gpt":0.2067232695161118,"score_spread":0.1964665823946372,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}