{"id":"W2413601527","doi":"10.1002/chem.201600999","title":"New Experimental Insight into the Nature of Metal−Metal Bonds in Digallium Compounds: <i>J</i> Coupling between Quadrupolar Nuclei","year":2016,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; American Chemical Society Petroleum Research Fund","keywords":"Gallium; Atomic orbital; Chemistry; Spin (aerodynamics); Context (archaeology); Metal; Chemical bond; Coupling constant; Crystallography; Resonance (particle physics); Boron; Coupling (piping); Main group element; Chemical physics; Computational chemistry; Atomic physics; Transition metal; Materials science; Physics; Organic chemistry; Nuclear physics; Thermodynamics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003343155,0.0002760644,0.0003132597,0.00003013181,0.0002062028,0.00005908699,0.0008707966,0.0001155827,0.0004669597],"category_scores_gemma":[0.00005522307,0.0001775231,0.0001762058,0.0001748257,0.000181853,0.0001932063,0.0002260116,0.001013105,0.00001396557],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001457616,"about_ca_system_score_gemma":0.00007495156,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005474893,"about_ca_topic_score_gemma":5.252027e-7,"domain_scores_codex":[0.9983702,0.00002928796,0.0006514519,0.0003166351,0.0003166934,0.0003157068],"domain_scores_gemma":[0.9986795,0.00009982198,0.0004213728,0.0005159909,0.00007011961,0.0002131923],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002186437,0.00006690328,0.0007361521,0.00002565189,0.00004435267,0.00002889855,0.0003979161,0.0000105635,0.9956844,0.00006059357,0.0007122397,0.002210501],"study_design_scores_gemma":[0.0008246848,0.0000201226,0.0001429566,0.0002353107,0.00003426393,0.000101676,0.0003446326,0.00004739089,0.9106051,0.0002512985,0.08713792,0.0002546548],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9737168,0.002298617,0.00228684,0.0006025525,0.0000231905,0.000066008,0.00002477976,0.00008986062,0.02089137],"genre_scores_gemma":[0.9951215,0.0001473166,0.002449054,0.00005135964,0.0006986344,0.000004783706,0.00001434342,0.00007025788,0.001442795],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08642567,"threshold_uncertainty_score":0.7239183,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01428523297744167,"score_gpt":0.2693988353199762,"score_spread":0.2551136023425346,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}