{"id":"W2415681988","doi":"10.1039/c6cc03904a","title":"An iron–oxygen intermediate formed during the catalytic cycle of cysteine dioxygenase","year":2016,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Canadian Institutes of Health Research","keywords":"Catalytic cycle; Cysteine; Dioxygenase; Catalysis; Chemistry; Oxygen; Enzyme; Absorption (acoustics); Photochemistry; Biochemistry; Organic chemistry; Materials science","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002702887,0.0002667331,0.0002995321,0.0001671686,0.0003256009,0.0003659044,0.0006609666,0.0005057667,0.000734792],"category_scores_gemma":[0.0005249302,0.0001891503,0.0002053246,0.0001514317,0.0003215141,0.0007458321,0.0002109305,0.0004250869,0.000168596],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000780408,"about_ca_system_score_gemma":0.0003921438,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001487872,"about_ca_topic_score_gemma":0.001019856,"domain_scores_codex":[0.9999248,0.000006197241,0.000002451892,0.00002409503,0.00002382199,0.00001857491],"domain_scores_gemma":[0.9999179,0.0000304885,0.00001713289,0.000008701809,0.00001481507,0.00001099093],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001240477,0.000515085,0.02121401,0.001223517,0.0002452371,0.001979758,0.000587189,0.06803392,0.7928807,0.04546206,0.002161109,0.06445689],"study_design_scores_gemma":[0.0002245278,0.0007550401,0.01399719,0.00006313859,0.0001487349,0.000596848,0.0002439996,0.3560844,0.5942664,0.02256143,0.0109522,0.0001060004],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9648429,0.0009164891,0.03044152,0.0001820513,0.00004157754,0.00003388897,0.0001944335,0.0003651533,0.002982143],"genre_scores_gemma":[0.9955844,0.0001969449,0.00358329,0.00001980733,0.000002503903,0.000009613879,0.0002049056,0.00001433219,0.0003842033],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001487872,"threshold_uncertainty_score":0.005662262,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01824797115976042,"score_gpt":0.2665251396593021,"score_spread":0.2482771684995417,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}