{"id":"W2416190356","doi":"10.1002/anie.201603627","title":"C−C Coupling of Benzyl Fluorides Catalyzed by an Electrophilic Phosphonium Cation","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":95,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Electrophile; Phosphonium; Silanes; Aryl; Catalysis; Chemistry; Allylic rearrangement; Cleavage (geology); Medicinal chemistry; Organic chemistry; Combinatorial chemistry; Materials science; Silane; Alkyl","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00027275,0.0001737732,0.0001643891,0.00005882936,0.00007334591,0.00001267772,0.0003358661,0.0002452029,0.003344844],"category_scores_gemma":[0.0002088716,0.0001539867,0.00007044487,0.0001101583,0.0001444273,0.0003482177,0.00005196628,0.000232854,0.00005622712],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002903479,"about_ca_system_score_gemma":0.00007625687,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005372004,"about_ca_topic_score_gemma":0.000007480541,"domain_scores_codex":[0.9987921,0.00001438443,0.0003682005,0.00031861,0.0002731892,0.0002334914],"domain_scores_gemma":[0.9989227,0.0002136045,0.000237214,0.0001929826,0.0003123682,0.0001211222],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000174589,0.0002191207,0.001143488,0.00002101999,0.00009964225,0.000002890845,0.00007418519,0.00001663651,0.9746109,0.0001893135,0.02237717,0.001071061],"study_design_scores_gemma":[0.001164893,0.00004578992,0.0002064135,0.00002782365,0.00004618078,0.00001694271,0.00002457989,0.0002172844,0.974166,0.0004921815,0.02341557,0.0001763788],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919388,0.0002556852,0.001212894,0.002618219,0.002107086,0.0001357151,0.0004576594,0.0001057009,0.001168263],"genre_scores_gemma":[0.9956244,0.0003680614,0.0000641995,0.0002057788,0.001527851,0.0000442274,0.00108605,0.00002741099,0.001051981],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003685662,"threshold_uncertainty_score":0.9975662,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0383114254543853,"score_gpt":0.3650260420927015,"score_spread":0.3267146166383162,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}