{"id":"W2416505126","doi":"10.1021/acs.inorgchem.5b02492","title":"“Ligands-with-Benefits”: Naphthalene-Substituted Schiff Bases Yielding New Ni<sup>II</sup> Metal Clusters with Ferromagnetic and Emissive Properties and Undergoing Exciting Transformations","year":2016,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Basic Energy Sciences; Natural Sciences and Engineering Research Council of Canada; Lawrence Berkeley National Laboratory; Comisión Interministerial de Ciencia y Tecnología; Alexander S. Onassis Public Benefit Foundation; Government of Ontario; Brock University; Research Corporation for Science Advancement; Camille and Henry Dreyfus Foundation; Fundação para a Ciência e a Tecnologia; U.S. Department of Energy","keywords":"Chemistry; Deprotonation; Ligand (biochemistry); Ferromagnetism; Naphthalene; Metal; Cluster (spacecraft); Yield (engineering); Schiff base; Crystallography; Stereochemistry; Photochemistry; Topology (electrical circuits); Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001382907,0.0003140665,0.0002820305,0.00005650597,0.0005095907,0.0002041623,0.0002230308,0.0001002635,0.0008082238],"category_scores_gemma":[0.0002171219,0.0002106339,0.0000253751,0.0001964617,0.0003035536,0.0006682844,0.0001346755,0.000120996,0.000006414359],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006280943,"about_ca_system_score_gemma":0.0002553712,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007756015,"about_ca_topic_score_gemma":0.00007609918,"domain_scores_codex":[0.9984263,0.00002215901,0.0003490696,0.0004988739,0.0003210595,0.0003825035],"domain_scores_gemma":[0.9990279,0.0002266267,0.0001538515,0.000269654,0.0001074333,0.0002145091],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006069383,0.00002204792,0.0005245896,0.0002838794,0.00002492697,0.000009896087,0.001283768,0.000205841,0.996272,0.00005819482,0.00006759471,0.001186591],"study_design_scores_gemma":[0.001769656,0.0001401399,0.0005301981,0.0009751259,0.00008698703,0.0008274177,0.001431232,0.0006622794,0.9929411,0.0001010315,0.00007084506,0.0004639956],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952942,0.0009339663,0.001044452,0.001399577,0.00003393268,0.0002308505,0.0000277642,0.0001680694,0.0008671583],"genre_scores_gemma":[0.9970594,0.00009796274,0.001748851,0.00005319409,0.00009869559,0.00002501688,0.000005533183,0.00003561703,0.0008757323],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003330886,"threshold_uncertainty_score":0.8849484,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01999093539284639,"score_gpt":0.1970190339724226,"score_spread":0.1770280985795762,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}