{"id":"W2416505126","doi":"10.1021/acs.inorgchem.5b02492","title":"“Ligands-with-Benefits”: Naphthalene-Substituted Schiff Bases Yielding New Ni<sup>II</sup> Metal Clusters with Ferromagnetic and Emissive Properties and Undergoing Exciting Transformations","year":2016,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"Basic Energy Sciences; Natural Sciences and Engineering Research Council of Canada; Lawrence Berkeley National Laboratory; Comisión Interministerial de Ciencia y Tecnología; Alexander S. Onassis Public Benefit Foundation; Government of Ontario; Brock University; Research Corporation for Science Advancement; Camille and Henry Dreyfus Foundation; Fundação para a Ciência e a Tecnologia; U.S. Department of Energy","keywords":"Chemistry; Deprotonation; Ligand (biochemistry); Ferromagnetism; Naphthalene; Metal; Cluster (spacecraft); Yield (engineering); Schiff base; Crystallography; Stereochemistry; Photochemistry; Topology (electrical circuits); Organic chemistry; Metallurgy","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005426121,0.0002615741,0.0001219023,0.0001013633,0.0001456517,0.0002407964,0.0003715248,0.0001965356,0.001148263],"category_scores_gemma":[0.0001305607,0.0001137356,0.00007416608,0.0001186888,0.0001951664,0.0002726647,0.000249076,0.0002552859,0.0003225939],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003072883,"about_ca_system_score_gemma":0.0001404383,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005526445,"about_ca_topic_score_gemma":0.001562453,"domain_scores_codex":[0.9999502,0.000006793191,0.000003412926,0.00001110505,0.00001525948,0.0000132297],"domain_scores_gemma":[0.9999591,0.000004000446,0.000009599471,0.000005524623,0.000007329693,0.00001439858],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002330565,0.00003477918,0.0002071772,0.0001403876,0.0000163334,0.0001606092,0.00007665549,0.000589031,0.9832124,0.003930001,0.0004327768,0.01096684],"study_design_scores_gemma":[0.00001608507,0.0001715737,0.0004728331,0.000003537257,0.00000863664,0.0001799872,0.00002003305,0.0009662225,0.991508,0.0002508464,0.00639438,0.000007921007],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9815081,0.0008618201,0.007596822,0.0001897374,0.00004207117,0.00004437389,0.0002062139,0.000339429,0.009211369],"genre_scores_gemma":[0.9909012,0.0003189116,0.005267938,0.00005352601,0.000007048322,0.00001910331,0.0001353471,0.00003113492,0.00326574],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001148263,"threshold_uncertainty_score":0.003841281,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01999093539284639,"score_gpt":0.1970190339724226,"score_spread":0.1770280985795762,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}