{"id":"W2417612115","doi":"10.1039/c6dt01869f","title":"Synthesis and characterization of five-coordinate, 16-electron Ru<sup>II</sup> complexes supported by tridentate bis(phosphino)silyl ligation","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Hospital Edmonton; University of Alberta; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Research Nova Scotia; Dalhousie University; Nova Scotia Research Innovation Trust","keywords":"Chemistry; Silylation; Electron; Medicinal chemistry; Crystallography; Stereochemistry; Catalysis; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001790855,0.0002208697,0.0002204499,0.0001256903,0.0001174284,0.0003740373,0.0003653719,0.0002405926,0.001475411],"category_scores_gemma":[0.0003515529,0.0001217171,0.000073414,0.0001389739,0.0001704654,0.0002152932,0.0002171629,0.0002002843,0.0004393518],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002226846,"about_ca_system_score_gemma":0.0001250464,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002665935,"about_ca_topic_score_gemma":0.0002931651,"domain_scores_codex":[0.9998826,0.00001888964,0.000009823508,0.00002691039,0.00004499432,0.00001684278],"domain_scores_gemma":[0.9998907,0.00001525022,0.00003203764,0.00001935435,0.00002258665,0.00002004864],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001163917,0.00001642783,0.0003271921,0.00005949207,0.000007353072,0.00006036121,0.00005347926,0.0002055557,0.995568,0.0002144289,0.00009165269,0.00327962],"study_design_scores_gemma":[0.0000085512,0.0001100729,0.0006848425,0.000002265538,0.000005592942,0.0001043627,0.00001176306,0.0004140688,0.9967462,0.00001692224,0.001892849,0.000002557756],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9925945,0.0006207663,0.003839446,0.00003679614,0.000007835069,0.0000351347,0.0002016442,0.00009367647,0.002570194],"genre_scores_gemma":[0.9938599,0.0002844323,0.003089383,0.00001536445,0.000003662045,0.00002174008,0.0003800275,0.000029344,0.002316087],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001475411,"threshold_uncertainty_score":0.004935801,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007602911803811887,"score_gpt":0.2105467801189917,"score_spread":0.2029438683151798,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}