{"id":"W2419539798","doi":"10.1039/c6qo00119j","title":"Reaction of alkenecarboxylic acids with isocyanates via rhodium(<scp>iii</scp>)-catalyzed C–H activation: a versatile route to cyclic imides","year":2016,"lang":"en","type":"article","venue":"Organic Chemistry Frontiers","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"China Scholarship Council; Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; McGill University","keywords":"Chemistry; Rhodium; Catalysis; Surface modification; Cascade; Combinatorial chemistry; Organic chemistry; Stereochemistry; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002893504,0.0004434747,0.000540438,0.00008632319,0.0002015733,0.00007038374,0.0004422435,0.0003182378,0.001049311],"category_scores_gemma":[0.0009228997,0.0003784393,0.00014685,0.0006838812,0.0001985155,0.0003531502,0.0001327199,0.0002030792,0.00003894401],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008639094,"about_ca_system_score_gemma":0.0002910543,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001274544,"about_ca_topic_score_gemma":0.00001082936,"domain_scores_codex":[0.9974837,0.00002891782,0.0005983171,0.0007870629,0.0006260975,0.0004759338],"domain_scores_gemma":[0.9975721,0.0003540835,0.0004999799,0.0009666491,0.0003050299,0.0003021396],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001202088,0.00008806779,0.003272591,0.0001493891,0.0002878523,0.000003087807,0.0002773307,0.00001173362,0.985779,0.00000611184,0.005632016,0.004372626],"study_design_scores_gemma":[0.001930037,0.00001823617,0.0007265775,0.0001556958,0.0001529331,0.00003921366,0.001006877,0.00004585914,0.9827042,0.0001728623,0.01279113,0.0002563349],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9126432,0.0000902938,0.0734866,0.0005169467,0.0002361145,0.0001962064,0.00008353855,0.0002796696,0.01246745],"genre_scores_gemma":[0.9736074,0.00004498822,0.005820244,0.00006918923,0.000445351,0.00007939985,0.0003437525,0.0001367422,0.01945299],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06766636,"threshold_uncertainty_score":0.9998667,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007550913640771468,"score_gpt":0.2167285420758878,"score_spread":0.2091776284351164,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}