{"id":"W2419539798","doi":"10.1039/c6qo00119j","title":"Reaction of alkenecarboxylic acids with isocyanates via rhodium(<scp>iii</scp>)-catalyzed C–H activation: a versatile route to cyclic imides","year":2016,"lang":"en","type":"article","venue":"Organic Chemistry Frontiers","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"China Scholarship Council; Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; McGill University","keywords":"Chemistry; Rhodium; Catalysis; Surface modification; Cascade; Combinatorial chemistry; Organic chemistry; Stereochemistry; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002430198,0.0007562051,0.0002499502,0.0002108206,0.0001481926,0.0002120032,0.0005026741,0.0004446679,0.001763256],"category_scores_gemma":[0.0001625663,0.0002246647,0.0003002234,0.0001697707,0.0002396149,0.000410734,0.0003448264,0.0007022296,0.0007129469],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003291511,"about_ca_system_score_gemma":0.0003253297,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006260536,"about_ca_topic_score_gemma":0.0009827127,"domain_scores_codex":[0.9998218,0.00002390609,0.00001305475,0.00004217782,0.00003067437,0.00006837647],"domain_scores_gemma":[0.9999373,0.00001088193,0.00001677489,0.00001029543,0.000009159584,0.0000155624],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001190406,0.00005686887,0.00008189422,0.0002141909,0.00001625045,0.0003957346,0.0001059687,0.000474681,0.9872643,0.002287569,0.0004615609,0.008522009],"study_design_scores_gemma":[0.00001593376,0.0002011846,0.0002094287,0.000005180073,0.000007352153,0.0001301884,0.000009759006,0.00051625,0.9952784,0.00008794162,0.003527291,0.00001114718],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9395564,0.004249456,0.02721817,0.0003932207,0.0002316771,0.000260342,0.0003830374,0.0004359444,0.02727184],"genre_scores_gemma":[0.9832363,0.001801489,0.007418169,0.00007825969,0.00003483965,0.00007568931,0.000220274,0.00004555914,0.007089515],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001763256,"threshold_uncertainty_score":0.005898654,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007550913640771468,"score_gpt":0.2167285420758878,"score_spread":0.2091776284351164,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}