{"id":"W2428650258","doi":"10.1021/acs.inorgchem.5b01434","title":"Mercury- and Cadmium-Assisted [2 + 2] Cyclodimerization of <i>tert</i>-Butylselenium Diimide","year":2015,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Magnus Ehrnroothin Säätiö; Suomen Kulttuurirahasto; Academy of Finland","keywords":"Chemistry; Diimide; Dimer; Acetonitrile; Tetrahydrofuran; Selenium; Ligand (biochemistry); Monomer; Medicinal chemistry; Metal; Stereochemistry; Crystallography; Molecule; Perylene; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001361184,0.0001327536,0.0003017935,0.00001815694,0.00002666474,0.00001155207,0.00007245989,0.00009658551,0.0001917279],"category_scores_gemma":[0.0002022836,0.0001085724,0.00004448818,0.0001180471,0.00009158235,0.00004843035,0.00006061836,0.0001087914,0.000009741368],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003269854,"about_ca_system_score_gemma":0.000118146,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006115717,"about_ca_topic_score_gemma":0.000001708228,"domain_scores_codex":[0.9991416,0.00001976303,0.0002821653,0.0001975064,0.0002208396,0.0001381135],"domain_scores_gemma":[0.9992923,0.00002737352,0.0001068572,0.0002677063,0.0001311186,0.0001746754],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009564324,0.00005606455,0.003881139,0.0002820283,0.00004587218,0.000003512993,0.000209927,2.341981e-7,0.9939861,0.000007885441,0.0004472698,0.0009843606],"study_design_scores_gemma":[0.0006148622,0.00005559416,0.005175698,0.00008377666,0.0001187062,0.0001905773,0.0001688766,0.00004483164,0.9887002,0.00004718688,0.004680227,0.0001195322],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9897965,0.001424194,0.00004746319,0.0004223803,0.00005882427,0.00009048331,0.000008185827,0.00004476052,0.008107224],"genre_scores_gemma":[0.9980063,0.0000641236,0.0004583771,0.0001229049,0.00009856083,0.000004529164,0.00002899639,0.00002152755,0.001194725],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008209771,"threshold_uncertainty_score":0.4427455,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04228993139210936,"score_gpt":0.2523569202701632,"score_spread":0.2100669888780538,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}