{"id":"W2435083699","doi":"10.1021/acs.orglett.6b01263","title":"Solution and Solid-Phase Stereocontrolled Synthesis of 1,2-<i>cis</i>-Glycopyranosides with Minimally Protected Glycopyranosyl Donors Catalyzed by BF<sub>3</sub>–<i>N</i>,<i>N</i>-Dimethylformamide Complex","year":2016,"lang":"en","type":"article","venue":"Organic Letters","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Catalysis; Stereoselectivity; Dimethylformamide; Glycopeptide; Glycosylation; Stereochemistry; Combinatorial chemistry; Organic chemistry; Solvent","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007543213,0.0005217949,0.0002334693,0.0001028323,0.0001456959,0.0002145702,0.0003239793,0.0001878198,0.001256782],"category_scores_gemma":[0.0000880946,0.0001488758,0.0001297103,0.0001378049,0.0001339862,0.0002090309,0.0001617514,0.0004850694,0.0006957846],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002196457,"about_ca_system_score_gemma":0.0002900364,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003227914,"about_ca_topic_score_gemma":0.000582803,"domain_scores_codex":[0.9999411,0.000009108052,0.000004438707,0.00001728724,0.00001533161,0.00001273998],"domain_scores_gemma":[0.9999537,0.000005154769,0.000016489,0.000006086344,0.000007469529,0.00001106087],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003902348,0.00001584682,0.00002969163,0.00004214924,0.000003505317,0.0000356376,0.000012811,0.0001842779,0.9956903,0.0004207275,0.00009744577,0.003428529],"study_design_scores_gemma":[0.000007456459,0.00008223876,0.0001069993,0.000001921264,0.000004376133,0.00009842859,0.000004607164,0.0003204345,0.9971554,0.00007294662,0.002140155,0.000004927046],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8632516,0.003500048,0.1089884,0.0002122704,0.0001847401,0.0003709365,0.001770778,0.001077935,0.0206434],"genre_scores_gemma":[0.945694,0.002290958,0.04680225,0.0000766283,0.00002094927,0.0001170307,0.0007601998,0.0001206393,0.004117477],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001256782,"threshold_uncertainty_score":0.004204392,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007092586839015812,"score_gpt":0.2130458518432821,"score_spread":0.2059532650042663,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}