{"id":"W2436599821","doi":"10.1021/acs.joc.5b01221","title":"Soluble Tetraaminotriptycene Precursors","year":2015,"lang":"fr","type":"article","venue":"The Journal of Organic Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts","keywords":"Chemistry; Pyrazine; Triptycene; Imidazole; Column chromatography; Molecule; Combinatorial chemistry; Organic chemistry; Chromatography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009431491,0.0003604167,0.0002057781,0.0001337665,0.0001429954,0.0002599134,0.0004145139,0.0003063172,0.00474715],"category_scores_gemma":[0.0001216722,0.0002342979,0.00009945233,0.0001910185,0.0001143998,0.0004120028,0.0002875101,0.0009215456,0.002101726],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002612795,"about_ca_system_score_gemma":0.0002481986,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004211921,"about_ca_topic_score_gemma":0.001415113,"domain_scores_codex":[0.9999005,0.000007675949,0.00001022708,0.00002450443,0.00003759186,0.00001956751],"domain_scores_gemma":[0.9998815,0.0000139124,0.00003251605,0.00001704485,0.00002853,0.00002652152],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002070091,0.000009253868,0.00002162844,0.00007670047,0.000003110098,0.00008698898,0.00002381932,0.00005564948,0.996252,0.0003160278,0.0001667889,0.002967459],"study_design_scores_gemma":[0.00001104309,0.0000953692,0.0001695509,0.000005536044,0.000006198756,0.0002077328,0.00001085143,0.0003068022,0.990698,0.00005716629,0.008427259,0.00000447254],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9021937,0.006447472,0.05955377,0.0005083444,0.0002222759,0.0003322425,0.002304591,0.0008698618,0.02756769],"genre_scores_gemma":[0.9294724,0.006597743,0.03296896,0.000182266,0.00004891304,0.0002151531,0.002685563,0.0002667114,0.02756241],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00474715,"threshold_uncertainty_score":0.01588082,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02619702411892233,"score_gpt":0.2380005294196656,"score_spread":0.2118035053007433,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}