{"id":"W2441860542","doi":"10.1021/acscatal.6b01105","title":"Confronting Neutrality: Maximizing Success in the Analysis of Transition-Metal Catalysts by MALDI Mass Spectrometry","year":2016,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Mass spectrometry; Analyte; Analytical Chemistry (journal); Electrospray ionization; Physical chemistry; Chromatography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005186501,0.0002371603,0.0005981609,0.0005706488,0.0001037423,0.00005013927,0.0007803192,0.0001346709,0.001373382],"category_scores_gemma":[0.00004817733,0.0001620493,0.0004274714,0.003380373,0.0001304015,0.0002133631,0.00004759159,0.0001900509,0.000006852215],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001128587,"about_ca_system_score_gemma":0.00002112455,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001059625,"about_ca_topic_score_gemma":0.0002067109,"domain_scores_codex":[0.9979946,0.00005007249,0.0006405712,0.0005058207,0.0004156005,0.0003933265],"domain_scores_gemma":[0.9982532,0.0002898067,0.0003055088,0.001019937,0.00006663031,0.00006495902],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001413188,0.0001800722,0.02190191,0.00005578897,0.001245118,0.000008998174,0.0003935695,0.00001172562,0.9710017,0.002622251,0.000308276,0.002256436],"study_design_scores_gemma":[0.0004946785,0.00001797857,0.007343517,0.00004565504,0.003367544,0.000008262173,0.001109999,0.0002042132,0.984714,0.001232296,0.0009865282,0.0004753424],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9849019,0.0002720336,0.006314594,0.002183135,0.000008880449,0.0001126611,0.0004813649,0.00008963442,0.005635785],"genre_scores_gemma":[0.9980043,0.0001063127,0.0007722029,0.00005641267,0.00003440045,0.00008872349,0.0005963523,0.00002199196,0.0003192703],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0145584,"threshold_uncertainty_score":0.9995395,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009474422414920322,"score_gpt":0.2479831124844363,"score_spread":0.238508690069516,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}