{"id":"W2460177690","doi":"10.1021/acs.joc.5b02187","title":"A Family of Routes to Substituted Phenols, Including Meta-Substituted Phenols","year":2015,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Phenols; Aromatization; Substituent; Deprotonation; Reagent; Electrophilic aromatic substitution; Electrophile; Organic chemistry; Benzene; Phenol; Medicinal chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001852095,0.0005616575,0.0002597936,0.0004562137,0.0002431016,0.0002386698,0.0005081025,0.0002962987,0.002722727],"category_scores_gemma":[0.0001546821,0.0002490085,0.0003492344,0.0002782787,0.0002529069,0.0005040625,0.0004213206,0.001023806,0.00131926],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003296479,"about_ca_system_score_gemma":0.0004309982,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003331362,"about_ca_topic_score_gemma":0.001041313,"domain_scores_codex":[0.9998678,0.00002011736,0.00001067664,0.00003016704,0.00003829524,0.00003289443],"domain_scores_gemma":[0.9999069,0.00001231488,0.00002874493,0.00001482689,0.00002032315,0.00001701508],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000182497,0.0001245128,0.0003852677,0.0009447413,0.00005791664,0.0006263668,0.0002138652,0.0008342913,0.9243994,0.008325609,0.001634402,0.06227113],"study_design_scores_gemma":[0.00006607742,0.001489922,0.001098028,0.00004718716,0.00004288789,0.00197808,0.00006211385,0.0008807341,0.8757721,0.001485487,0.1170315,0.00004576578],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6122673,0.05652789,0.2555152,0.001292409,0.0009717239,0.0007314577,0.003268572,0.002461116,0.06696438],"genre_scores_gemma":[0.8410134,0.03108817,0.09078418,0.0005430171,0.0001690787,0.000318344,0.001363098,0.0003141718,0.03440668],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002722727,"threshold_uncertainty_score":0.009108484,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1061923901976191,"score_gpt":0.2910366108442413,"score_spread":0.1848442206466222,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}