{"id":"W2460901924","doi":"10.1039/c6dt01930g","title":"Theoretical investigation of low-valent uranium and transuranium complexes of a flexible small-cavity macrocycle: structural, formation reaction and redox properties","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Winnipeg; University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China","keywords":"Actinide; Uranium; Transuranium element; Redox; Chemistry; Ion; Inorganic chemistry; Crystallography; Materials science; Metallurgy; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001135891,0.0001478498,0.0002012458,0.00004548305,0.000155351,0.00001805706,0.00005929066,0.0001048674,0.000222299],"category_scores_gemma":[0.00001093748,0.0001105173,0.00004957542,0.00008390509,0.0005280001,0.0004115051,0.000003759744,0.0001172529,2.997228e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003685436,"about_ca_system_score_gemma":0.0000273272,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002955386,"about_ca_topic_score_gemma":0.00000808384,"domain_scores_codex":[0.9990931,0.0000325535,0.0003659038,0.0002067563,0.0001534722,0.0001481995],"domain_scores_gemma":[0.999444,0.00007902939,0.0001675809,0.000136317,0.00009736047,0.00007573262],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002466401,0.0000249719,0.0004020197,0.001286447,0.00004441792,2.336069e-7,0.0011767,0.000003896556,0.9880339,0.0009794231,0.000001791915,0.007799585],"study_design_scores_gemma":[0.0007531375,0.00003361267,0.001457801,0.0003639874,0.00008641879,0.00003835142,0.0005403596,0.000252533,0.9942775,0.002044377,0.00001557845,0.0001363225],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9904859,0.0002073823,0.008124072,0.000323279,0.00003418508,0.0001054058,0.0001434445,0.00004531601,0.0005309999],"genre_scores_gemma":[0.999312,0.0001860366,0.0003563697,0.000006168433,0.00002570657,0.00001897533,0.00001981299,0.00001215157,0.00006275885],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008826105,"threshold_uncertainty_score":0.4506765,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0206806449476163,"score_gpt":0.2343510553149856,"score_spread":0.2136704103673693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}