{"id":"W2460977218","doi":"10.1002/cctc.201600447","title":"A New Route to Phenols: Palladium‐Catalyzed Cyclization and Oxidation of γ,δ‐Unsaturated Ketones","year":2016,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Palladium; Cyclohexanone; Phenols; Enol; Chemistry; Phenol; Catalysis; Ketone; Alkene; Organic chemistry; Substrate (aquarium); Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000167568,0.0005429897,0.0001886634,0.0003861483,0.0002654109,0.0003197485,0.0003851966,0.000300694,0.001804183],"category_scores_gemma":[0.0001091153,0.0002212668,0.0002324458,0.0002134849,0.0003137582,0.0005720191,0.0004576081,0.0007757088,0.0008045745],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003223056,"about_ca_system_score_gemma":0.0005074542,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004961707,"about_ca_topic_score_gemma":0.0008687,"domain_scores_codex":[0.9998858,0.00001407815,0.00001081006,0.00002768956,0.00002606791,0.00003547846],"domain_scores_gemma":[0.999929,0.000007262453,0.00001604295,0.00000947761,0.00001120236,0.00002703032],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002130451,0.0002388954,0.0004137457,0.0007678258,0.00005482084,0.001673991,0.0004075843,0.001457355,0.9319829,0.009322961,0.001308582,0.05215833],"study_design_scores_gemma":[0.0001010598,0.001151248,0.0009819878,0.00004507259,0.00005373001,0.002295589,0.0001185803,0.001268795,0.9317135,0.00197662,0.06023385,0.00005989707],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.796949,0.02163748,0.128213,0.001501549,0.0008448392,0.0004075383,0.00119271,0.0009483992,0.04830545],"genre_scores_gemma":[0.9566762,0.009915091,0.02212447,0.00024077,0.00008091014,0.00007952542,0.0003180519,0.00006442499,0.01050052],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001804183,"threshold_uncertainty_score":0.006035566,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02048621891083948,"score_gpt":0.2709624268134628,"score_spread":0.2504762079026233,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}