{"id":"W2462364112","doi":"10.1063/1.4954941","title":"Torsionally mediated spin-rotation hyperfine splittings at moderate to high <i>J</i> values in methanol","year":2016,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Natural Sciences and Engineering Research Council of Canada; Federal Agency for Science and Innovation","keywords":"Hyperfine structure; Angular momentum; Rotation (mathematics); Degenerate energy levels; Physics; Torsion (gastropod); Atomic physics; Total angular momentum quantum number; Spin (aerodynamics); Quantum number; Quantum mechanics; Geometry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001458637,0.0002056561,0.0001064992,0.0004367335,0.0003389607,0.0001496913,0.0003651971,0.0002663778,0.001388824],"category_scores_gemma":[0.0003199436,0.000125601,0.0001020924,0.0002790034,0.0004750906,0.0004528081,0.0002900378,0.0002659669,0.0001334358],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002081362,"about_ca_system_score_gemma":0.00008494378,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003285833,"about_ca_topic_score_gemma":0.0005282865,"domain_scores_codex":[0.9999295,0.000008211662,0.000003072225,0.00002024552,0.00001689511,0.00002197574],"domain_scores_gemma":[0.9998918,0.00003138809,0.00003311268,0.00001241709,0.00001287989,0.0000184222],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002515188,0.00003528271,0.01264443,0.0001229116,0.00001970758,0.0006729021,0.0004510298,0.001577138,0.9694677,0.004137933,0.0001440513,0.01047541],"study_design_scores_gemma":[0.00007632485,0.0004769885,0.0846466,0.00003428397,0.00005613813,0.001086022,0.001333653,0.01767943,0.8784863,0.01330322,0.002748798,0.00007213932],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9933119,0.0002500262,0.00453316,0.00009504896,0.00001028532,0.000006668115,0.0000374348,0.0000571573,0.001698284],"genre_scores_gemma":[0.9994166,0.00004338856,0.0003796992,0.00001166552,0.000003036146,0.000003040973,0.00001594791,0.000004563291,0.0001221173],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001388824,"threshold_uncertainty_score":0.004646063,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006663785584389847,"score_gpt":0.2416486155607611,"score_spread":0.2349848299763713,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}