{"id":"W2464279834","doi":"10.1039/c6dt02105k","title":"On the mechanism of Ni(<scp>ii</scp>)-promoted Michael-type hydroamination of acrylonitrile and its substituted derivatives","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Montréal","keywords":"Chemistry; Nucleophile; Cationic polymerization; Hydroamination; Medicinal chemistry; Electrophile; Nitrile; Adduct; Acrylonitrile; Amine gas treating; Oxazoline; Ligand (biochemistry); Substituent; Michael reaction; Nucleophilic addition; Stereochemistry; Catalysis; Polymer chemistry; Organic chemistry; Copolymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008223996,0.00174872,0.001317025,0.0004286428,0.0009202465,0.0005771231,0.002714717,0.001609825,0.01722531],"category_scores_gemma":[0.001854118,0.0008381159,0.0009904946,0.0006638941,0.001287422,0.001979665,0.001115294,0.004489531,0.005779304],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001205288,"about_ca_system_score_gemma":0.00145277,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002372094,"about_ca_topic_score_gemma":0.002870693,"domain_scores_codex":[0.9993122,0.00005484872,0.00006417064,0.0001131645,0.0002932607,0.0001623805],"domain_scores_gemma":[0.9994565,0.0001349223,0.00008988216,0.00008119294,0.0001627478,0.00007487638],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001268371,0.00015213,0.0003634134,0.01235243,0.0002357425,0.004558176,0.0006242662,0.002181256,0.3942964,0.03709378,0.4138635,0.1330106],"study_design_scores_gemma":[0.0001372827,0.000652246,0.001401933,0.0002428789,0.0001463501,0.002929837,0.0001637137,0.002744169,0.3720902,0.005713003,0.6135814,0.0001970522],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"editorial","genre_gemma":"empirical","genre_scores_codex":[0.1270422,0.1487787,0.07289732,0.07447269,0.5216611,0.0007199598,0.003777223,0.005879506,0.04477118],"genre_scores_gemma":[0.605331,0.1217821,0.0329491,0.01215108,0.01689745,0.0006706638,0.00286765,0.001062711,0.2062883],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01722531,"threshold_uncertainty_score":0.05762434,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0188111838758545,"score_gpt":0.2397520506510545,"score_spread":0.2209408667752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}