{"id":"W2464279834","doi":"10.1039/c6dt02105k","title":"On the mechanism of Ni(<scp>ii</scp>)-promoted Michael-type hydroamination of acrylonitrile and its substituted derivatives","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Montréal","keywords":"Chemistry; Nucleophile; Cationic polymerization; Hydroamination; Medicinal chemistry; Electrophile; Nitrile; Adduct; Acrylonitrile; Amine gas treating; Oxazoline; Ligand (biochemistry); Substituent; Michael reaction; Nucleophilic addition; Stereochemistry; Catalysis; Polymer chemistry; Organic chemistry; Copolymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002080721,0.0001791188,0.0002294961,0.0001387022,0.0001688122,0.000007047662,0.0002020757,0.0001707855,0.0002559265],"category_scores_gemma":[0.0003894377,0.0001221223,0.00007637006,0.0002731923,0.0001455213,0.0001430225,0.000009360646,0.000140798,0.000005450684],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000423345,"about_ca_system_score_gemma":0.00004835162,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002854951,"about_ca_topic_score_gemma":0.00001904933,"domain_scores_codex":[0.9989502,0.00006283666,0.0003149326,0.0002499077,0.0002413919,0.0001807638],"domain_scores_gemma":[0.9981561,0.001055685,0.0002033711,0.000346148,0.0001881597,0.0000505695],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002226055,0.0001794223,0.0000137009,0.0000633357,0.00006711933,6.957038e-7,0.0005462833,0.000002087814,0.9912732,0.005554411,0.00003076954,0.002246707],"study_design_scores_gemma":[0.000322436,0.00008386179,0.0001334718,0.0001953124,0.00005759784,0.000003871861,0.0002225467,0.0001785449,0.9957698,0.00277896,0.0001848568,0.00006873879],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9811159,0.00008347267,0.01684283,0.0002860592,0.00005295032,0.0001875034,0.0001892636,0.0001411351,0.001100936],"genre_scores_gemma":[0.9988666,0.0001522408,0.0003504749,0.00001527503,0.00001393235,0.00005035512,0.00001112464,0.00002769899,0.0005122619],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01775078,"threshold_uncertainty_score":0.4980001,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0188111838758545,"score_gpt":0.2397520506510545,"score_spread":0.2209408667752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}