{"id":"W2465052894","doi":"10.1107/s205698901600935x","title":"Crystal structures of bis(phenoxy)silicon phthalocyanines: increasing π–π interactions, solubility and disorder and no halogen bonding observed","year":2016,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Crystallographic Communications","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; University of Ottawa","funders":"","keywords":"Phthalocyanine; Silicon; Solubility; Stacking; Halogen; Chemistry; Crystal (programming language); Crystallography; Single crystal; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001015645,0.000510649,0.0006180654,0.0005963312,0.0008727192,0.000158652,0.0009010813,0.000290816,0.0002936233],"category_scores_gemma":[0.0006181438,0.0004241974,0.0002448827,0.0009442788,0.002143208,0.0008374827,0.0009402229,0.000422018,4.173822e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000571975,"about_ca_system_score_gemma":0.00009570124,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001101264,"about_ca_topic_score_gemma":0.001035517,"domain_scores_codex":[0.9966403,0.0005928091,0.001007014,0.0008364445,0.000369842,0.0005535446],"domain_scores_gemma":[0.9953426,0.00126983,0.0006542993,0.001966679,0.0004543949,0.0003122015],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.0001359305,0.0002063778,0.1230212,0.0001344366,0.0000981667,0.000001135416,0.0001796385,9.639757e-7,0.8749106,0.0009346982,0.0001042547,0.0002725979],"study_design_scores_gemma":[0.005861387,0.0008378114,0.8412625,0.001089543,0.0006826597,0.001526121,0.00318349,0.0003576246,0.01993451,0.01424748,0.1081669,0.002850003],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946161,0.001401358,0.0003842732,0.0009502806,0.0002646269,0.0004645992,0.0002197957,0.0002738019,0.001425177],"genre_scores_gemma":[0.9955204,0.001583034,0.002423863,0.00004891646,0.00008581661,0.00010331,0.00008356851,0.00005838495,0.00009266592],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.8549761,"threshold_uncertainty_score":0.999821,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02758727648217271,"score_gpt":0.2608276931416234,"score_spread":0.2332404166594506,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}