{"id":"W2465052894","doi":"10.1107/s205698901600935x","title":"Crystal structures of bis(phenoxy)silicon phthalocyanines: increasing π–π interactions, solubility and disorder and no halogen bonding observed","year":2016,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Crystallographic Communications","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; University of Ottawa","funders":"","keywords":"Phthalocyanine; Silicon; Solubility; Stacking; Halogen; Chemistry; Crystal (programming language); Crystallography; Single crystal; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006122846,0.0001258019,0.00008922562,0.0001061454,0.0001169207,0.000145558,0.0001799336,0.0001396031,0.001063887],"category_scores_gemma":[0.0001814096,0.0001075303,0.00006408236,0.0001678317,0.0001358537,0.0001117835,0.0000761374,0.0003603134,0.00009527226],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003024089,"about_ca_system_score_gemma":0.00019943,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001266318,"about_ca_topic_score_gemma":0.001924657,"domain_scores_codex":[0.9999493,0.000006049387,0.000002561044,0.00001026405,0.00002254717,0.000009274651],"domain_scores_gemma":[0.9998875,0.00002704384,0.00003232319,0.000007125372,0.00002815321,0.00001789546],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001653997,0.00004823187,0.00126981,0.0001073818,0.000008641744,0.0001051382,0.00007901534,0.0008043186,0.9935142,0.0004897164,0.0005401655,0.002867979],"study_design_scores_gemma":[0.00009017327,0.0003389397,0.009958866,0.00000821201,0.00001401585,0.0001939332,0.00007515307,0.009057341,0.9776576,0.0001090375,0.002486578,0.00001010368],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978203,0.000208293,0.0003849734,0.00004379062,0.000006289221,0.000007929588,0.0003161846,0.00002709506,0.001185089],"genre_scores_gemma":[0.9964092,0.0001891828,0.001736102,0.00001579573,0.000004036103,0.00002642216,0.0006085556,0.00001682749,0.0009938012],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001266318,"threshold_uncertainty_score":0.003559053,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02758727648217271,"score_gpt":0.2608276931416234,"score_spread":0.2332404166594506,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}