{"id":"W2465501103","doi":"10.5935/0100-4042.20160111","title":"SULFONIC ACID-FUNCTIONALIZED LUS-1: AN EFFICIENT CATALYST FOR ONE-POT SYNTHESIS OF 2,4-DIAMINO PYRIMIDINE-5-CARBONITRILE DERIVATIVES","year":2016,"lang":"en","type":"article","venue":"Química Nova","topic":"Multicomponent Synthesis of Heterocycles","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Alzahra University; University of Tehran","keywords":"Sulfonic acid; Catalysis; Pyrimidine; Solid acid; Chemistry; Organic chemistry; Combinatorial chemistry; Stereochemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002950808,0.0003877595,0.0006807416,0.0001806232,0.0001321974,0.00002939951,0.0006169403,0.0002117668,0.002667915],"category_scores_gemma":[0.0008688471,0.0003057525,0.0003266326,0.00009417276,0.0002940065,0.0001633964,0.00011989,0.00009721203,0.00007575749],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002080281,"about_ca_system_score_gemma":0.00009158085,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009416774,"about_ca_topic_score_gemma":0.00002466331,"domain_scores_codex":[0.997461,0.00006334203,0.000746551,0.0006962893,0.0004847535,0.0005480961],"domain_scores_gemma":[0.9965346,0.001721791,0.0004272767,0.0009594279,0.0001745481,0.0001823044],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005578743,0.0006802229,0.0009014703,0.0002391602,0.0002266503,0.000001403276,0.00006883377,0.00001915179,0.9872012,0.0002754404,0.0000768955,0.009751696],"study_design_scores_gemma":[0.001412281,0.00002682972,0.00294014,0.000299141,0.0001546612,0.000005372906,0.0001007011,0.0005482053,0.9925862,0.0001203634,0.001381157,0.0004249787],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955105,0.0001666262,0.0009579276,0.0004807073,0.0001579674,0.0002164632,0.0004192622,0.0001802938,0.001910288],"genre_scores_gemma":[0.9956725,0.00001934903,0.003476364,0.00001790398,0.0002140801,0.0001958986,0.00006486682,0.0000877352,0.0002513223],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009326717,"threshold_uncertainty_score":0.9999394,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0471135739551818,"score_gpt":0.2771807237208587,"score_spread":0.2300671497656769,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}