{"id":"W2466354855","doi":"10.1039/c6dt02181f","title":"Synthesis and catalytic applications of 1,2,3-triazolylidene gold(<scp>i</scp>) complexes in silver-free oxazoline syntheses and C–H bond activation","year":2016,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"Toronto Metropolitan University","funders":"Irish Research Council; European Cooperation in Science and Technology; European Science Foundation; Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía; University of Bern; Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung; European Research Council; Junta de Andalucía; National Science Foundation","keywords":"Chemistry; Oxazoline; Catalysis; Chloride; Ethyl diazoacetate; Styrene; Carbene; Regioselectivity; Combinatorial chemistry; Polymer chemistry; Medicinal chemistry; Organic chemistry; Cyclopropanation; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003050455,0.0004334073,0.0002718527,0.0002329914,0.0001922823,0.0004390284,0.0005166425,0.0004071984,0.0009759738],"category_scores_gemma":[0.0003275583,0.0002300448,0.0003237623,0.000184847,0.0003233027,0.0002749311,0.0003675978,0.0003291006,0.0003904304],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006662447,"about_ca_system_score_gemma":0.0002227209,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000690156,"about_ca_topic_score_gemma":0.00150731,"domain_scores_codex":[0.9997354,0.00004432044,0.00004050181,0.00005518893,0.00006757802,0.00005700243],"domain_scores_gemma":[0.9998596,0.00002512248,0.00004389514,0.00002015253,0.00003089157,0.00002039148],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004013857,0.00001144643,0.00009860466,0.0001353212,0.000007485093,0.0001136815,0.00007070188,0.0001695955,0.9967893,0.0002239482,0.00005748905,0.002282218],"study_design_scores_gemma":[0.000007739772,0.00009704744,0.0002060797,0.000003293562,0.000007470859,0.0001670152,0.0000117908,0.0003098134,0.9984087,0.00001851619,0.0007576598,0.000004858016],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9789924,0.004215863,0.01074307,0.0001770388,0.00003314635,0.00008038123,0.0001671336,0.0002486768,0.005342303],"genre_scores_gemma":[0.9908602,0.001033669,0.006275925,0.00003457398,0.000005843139,0.00003296618,0.0001429148,0.00003056682,0.00158332],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009759738,"threshold_uncertainty_score":0.004833996,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01470366793231469,"score_gpt":0.2309784110455242,"score_spread":0.2162747431132095,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}