{"id":"W2466628073","doi":"10.1021/acs.jpcb.5b01752","title":"Radiosensitization of DNA by Cisplatin Adducts Results from an Increase in the Rate Constant for the Reaction with Hydrated Electrons and Formation of Pt<sup>I</sup>","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Radiation Effects and Dosimetry","field":"Agricultural and Biological Sciences","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Canadian Institutes of Health Research","keywords":"Radiolysis; Adduct; Chemistry; Reaction rate constant; Cisplatin; Solvated electron; Electron; Moiety; Photochemistry; Reaction mechanism; Oligonucleotide; Diffusion; Kinetics; Radical; Radiochemistry; Physical chemistry; DNA; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002161016,0.0005147441,0.0004542754,0.000156568,0.000110057,0.000263496,0.0003653712,0.0004140583,0.002651092],"category_scores_gemma":[0.0007902413,0.0002777766,0.0002654172,0.0001534067,0.0004763149,0.0004296893,0.0002468459,0.0007347395,0.0006913198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004250872,"about_ca_system_score_gemma":0.0001928658,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003915458,"about_ca_topic_score_gemma":0.0003490735,"domain_scores_codex":[0.9998216,0.00003522606,0.00001014341,0.00006546579,0.00004561653,0.00002198288],"domain_scores_gemma":[0.9995342,0.0001895563,0.0001393367,0.00003567903,0.00006148966,0.00003976524],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008529155,0.000007269755,0.0003057602,0.00005715527,0.00001222447,0.0000268602,0.00003877249,0.000191474,0.9972413,0.0001640248,0.00002204877,0.001847881],"study_design_scores_gemma":[0.000004366812,0.0001777562,0.001460792,0.000003710709,0.00001247086,0.0001449482,0.00001457253,0.0005304787,0.9968923,0.00006854865,0.0006849344,0.000005181719],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.960952,0.003628142,0.0316872,0.0001365817,0.00006561133,0.0001236568,0.000289316,0.0002917832,0.002825751],"genre_scores_gemma":[0.9891624,0.0008786895,0.007721064,0.00004196168,0.000007078874,0.00003907371,0.000195341,0.00004571395,0.001908613],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002651092,"threshold_uncertainty_score":0.008868814,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01029673139191102,"score_gpt":0.2176911072695915,"score_spread":0.2073943758776805,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}