{"id":"W2466831159","doi":"10.1021/acs.joc.6b00782","title":"DABO Boronate Promoted Conjugate Allylation of α,β-Unsaturated Aldehydes Using Copper(II) Catalysis","year":2016,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; University of Toronto","keywords":"Chemistry; Conjugate; Aldehyde; Catalysis; Reagent; Alkyl; Aryl; Organic chemistry; Combinatorial chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006745282,0.0002289424,0.0004919088,0.00005581063,0.0001474065,0.00001825738,0.0005987847,0.0001741397,0.002282924],"category_scores_gemma":[0.0005747465,0.0001274891,0.0002235571,0.000492882,0.0001644666,0.0001772795,0.0001260216,0.0002239899,0.000005681562],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002039708,"about_ca_system_score_gemma":0.0002195418,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000220346,"about_ca_topic_score_gemma":0.00000209857,"domain_scores_codex":[0.9981607,0.00003974962,0.0008634151,0.0001658348,0.0005230476,0.0002472827],"domain_scores_gemma":[0.9972187,0.0002732217,0.00142244,0.000510762,0.0004622601,0.0001126705],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001149682,0.0001042351,0.0004827555,0.00006727751,0.0004898536,0.000006543278,0.0002341091,0.00001089526,0.9923292,6.954622e-7,0.0001357452,0.006023765],"study_design_scores_gemma":[0.0007301262,0.00001881936,0.0001628358,0.0002157767,0.0006861152,0.0002369803,0.0004218553,0.0001034268,0.9969362,0.00004168725,0.0002728696,0.0001733295],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969492,0.0008582535,0.000324896,0.0003915578,0.00003605667,0.00002991696,0.00002430192,0.00001908164,0.001366736],"genre_scores_gemma":[0.9984664,0.0003202801,0.0001502962,0.00001223122,0.0001902069,5.18792e-7,0.000009771094,0.00003663665,0.000813619],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005850435,"threshold_uncertainty_score":0.9986292,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0121768466959217,"score_gpt":0.220159417643339,"score_spread":0.2079825709474173,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}