{"id":"W2468034639","doi":"10.1021/jacs.5b10993","title":"Exclusive Csp<sup>3</sup>–Csp<sup>3</sup> vs Csp<sup>2</sup>–Csp<sup>3</sup> Reductive Elimination from Pt<sup>IV</sup> Governed by Ligand Constraints","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"American Chemical Society Petroleum Research Fund; Canada Foundation for Innovation; Natural Sciences and Engineering Research Council of Canada; University of British Columbia; Government of Canada","keywords":"Chemistry; Ligand (biochemistry); Reactivity (psychology); Bromide; Reductive elimination; Thermal decomposition; Medicinal chemistry; Radiochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001079535,0.0002602383,0.0001587574,0.00005751701,0.0001425286,0.0002877857,0.0003205723,0.0002015027,0.003116266],"category_scores_gemma":[0.0002294422,0.0001478201,0.0001074222,0.0001020235,0.000320138,0.0002401915,0.0002295262,0.0004052992,0.0003763837],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002746544,"about_ca_system_score_gemma":0.0002401609,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007500502,"about_ca_topic_score_gemma":0.001779901,"domain_scores_codex":[0.9998889,0.000008422136,0.000004293695,0.00002161875,0.00003728925,0.00003945454],"domain_scores_gemma":[0.9999057,0.00002804431,0.00002881634,0.00001283666,0.00001408904,0.00001046745],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003301684,0.00001171329,0.0002660528,0.00007938366,0.000008279789,0.0001385868,0.0000407338,0.0004768505,0.9954646,0.0010354,0.0001655662,0.001982722],"study_design_scores_gemma":[0.000007944721,0.00004694877,0.0005117729,0.000001605318,0.000002610657,0.00009289529,0.00002163087,0.001033471,0.9975398,0.00007360939,0.0006652839,0.000002414553],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9913611,0.0002053372,0.002463958,0.00006606029,0.00001150306,0.00001157871,0.00018859,0.00006996347,0.005622032],"genre_scores_gemma":[0.998226,0.00010561,0.0004856002,0.00001669145,0.000001837929,0.000005553095,0.0001191452,0.000022398,0.001017195],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003116266,"threshold_uncertainty_score":0.01042497,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01155678544847178,"score_gpt":0.2458132040163954,"score_spread":0.2342564185679236,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}