{"id":"W2470563699","doi":"10.1021/acs.joc.6b01032","title":"Determination of Key Hydrocarbon Autoxidation Products by Fluorescence","year":2016,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation; University of Ottawa","keywords":"Chemistry; Autoxidation; Conjugated system; Titration; Organic chemistry; Hydrocarbon; Protonation; Carboxylic acid; Iodometry; Solvent; Photochemistry; Fluorescence; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004104858,0.0006074964,0.0002976396,0.0004683741,0.0002659991,0.0002366086,0.0002940561,0.0004359769,0.001285185],"category_scores_gemma":[0.0003961526,0.0001926051,0.0002007592,0.0003174349,0.0003198707,0.0003366484,0.0002931455,0.0006485998,0.000433162],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002943057,"about_ca_system_score_gemma":0.000257232,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007965846,"about_ca_topic_score_gemma":0.001478584,"domain_scores_codex":[0.9996887,0.00004236978,0.0000155192,0.00009677401,0.0001014696,0.00005525471],"domain_scores_gemma":[0.9997275,0.00007438516,0.00006326354,0.0000249152,0.00008395193,0.00002598999],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001855278,0.000007909189,0.0001374921,0.00002342005,0.00000269951,0.000009004213,0.00001825884,0.00004159541,0.9984285,0.00003278887,0.00001836085,0.001261336],"study_design_scores_gemma":[0.000001525116,0.00005173612,0.000683547,0.000002889418,0.000003731063,0.00002450152,0.00001188223,0.0004244104,0.9981878,0.00002303448,0.0005816206,0.000003327159],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9106486,0.003447403,0.08170014,0.0001117329,0.00004567392,0.0001389502,0.001003121,0.0004178485,0.00248655],"genre_scores_gemma":[0.900947,0.004796171,0.08575023,0.0001004657,0.00003138087,0.000393185,0.001361755,0.00007635335,0.006543436],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001285185,"threshold_uncertainty_score":0.004299402,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006348604593959772,"score_gpt":0.2041330305168786,"score_spread":0.1977844259229188,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}