{"id":"W2471086228","doi":"10.1002/anie.201602795","title":"Luminescent Gold Nanoparticles with Size‐Independent Emission","year":2016,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":163,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; National Institute of Diabetes and Digestive and Kidney Diseases; University of Texas at Dallas; National Institutes of Health; Cancer Prevention and Research Institute of Texas","keywords":"Photoluminescence; Nanoparticle; Fluorescence; Luminescence; Absorption (acoustics); Surface charge; Colloidal gold; Circular dichroism; Materials science; Photochemistry; Ligand (biochemistry); Spectroscopy; Chemistry; Analytical Chemistry (journal); Nanotechnology; Crystallography; Physical chemistry; Optoelectronics; Optics; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001351435,0.0001147541,0.0000932627,0.00003111959,0.00006236324,0.00006329453,0.0002286201,0.0000479209,0.001482785],"category_scores_gemma":[0.00007689452,0.00006853578,0.00003881477,0.00005943578,0.00006528143,0.0003222623,0.00005627292,0.00003310642,0.0002255948],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001149389,"about_ca_system_score_gemma":0.00002949331,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001478541,"about_ca_topic_score_gemma":0.000009532628,"domain_scores_codex":[0.9989394,0.0000125567,0.0001945751,0.000282877,0.000404051,0.000166555],"domain_scores_gemma":[0.9993445,0.000117462,0.0001151145,0.0001847447,0.0001536634,0.00008450772],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004822955,0.00008642436,0.0003219171,0.00000434366,0.000007191733,0.000003504289,0.00003261322,7.3215e-7,0.9841226,0.0002807031,0.01372969,0.00136208],"study_design_scores_gemma":[0.0004820072,0.00002684806,0.0009722536,0.0001147514,0.00001099795,0.00001859066,0.00002910973,0.000004369856,0.9758231,0.0003356525,0.02205786,0.0001244497],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9791871,0.00003346934,0.006778026,0.007719432,0.0007875473,0.0001719901,0.0001082756,0.0001325193,0.005081695],"genre_scores_gemma":[0.9952698,0.00003087582,0.0006035455,0.0001962026,0.0007444566,0.00009557113,0.00001840147,0.00001367837,0.003027515],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01608271,"threshold_uncertainty_score":0.99943,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01168803526954743,"score_gpt":0.2383077718275599,"score_spread":0.2266197365580124,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}