{"id":"W2471152204","doi":"10.1021/acs.inorgchem.6b01112","title":"Interactions between SF<sub>4</sub> and Fluoride: A Crystallographic Study of Solvolysis Products of SF<sub>4</sub>·Nitrogen-Base Adducts by HF","year":2016,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Canada Foundation for Innovation; Natural Sciences and Engineering Research Council of Canada; Government of Canada","keywords":"Chemistry; Pyridinium; Adduct; Protonation; Fluoride; Raman spectroscopy; Solvolysis; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Crystallography; Stereochemistry; Ion; Inorganic chemistry; Organic chemistry; Hydrolysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001094283,0.0003072268,0.0002588898,0.0002083085,0.0005120179,0.000306133,0.000466434,0.0003478143,0.003324612],"category_scores_gemma":[0.0002114726,0.0002524747,0.0002411873,0.0002882347,0.0005225819,0.000334139,0.0002554313,0.000562505,0.000257897],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007605815,"about_ca_system_score_gemma":0.0003183596,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.01067841,"about_ca_topic_score_gemma":0.007098455,"domain_scores_codex":[0.9998766,0.000008462772,0.000005090256,0.00003125013,0.00005105754,0.00002753633],"domain_scores_gemma":[0.9999013,0.00002404108,0.00003077001,0.000005717008,0.00002781836,0.00001043588],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002948738,0.00002573158,0.0047619,0.0001414336,0.00004453656,0.0003224683,0.0003699054,0.0007726168,0.9874899,0.0003458304,0.0005806476,0.00485011],"study_design_scores_gemma":[0.00005233069,0.0001803546,0.03263451,0.00002392584,0.00004984532,0.0006896478,0.0005437369,0.002994098,0.9542121,0.00011327,0.008475729,0.00003051672],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961258,0.0004144242,0.000807588,0.00008071857,0.000007828807,0.00001156105,0.0003539461,0.00003482546,0.00216336],"genre_scores_gemma":[0.9939094,0.0004617853,0.002412367,0.00004850495,0.0000100907,0.0000317182,0.000935196,0.00004797703,0.002143173],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01067841,"threshold_uncertainty_score":0.02123249,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009262795621495222,"score_gpt":0.2053128328429725,"score_spread":0.1960500372214773,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}