{"id":"W2471713401","doi":"10.1002/slct.201600713","title":"Highly Ordered Rectangular Columnar Ionic Liquid Crystals: A More Efficient Medium for Intramolecular Diels Alder Reactions","year":2016,"lang":"en","type":"article","venue":"ChemistrySelect","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Université de Montréal; Centre in Green Chemistry and Catalysis","keywords":"Intramolecular force; Ionic liquid; Diels–Alder reaction; Yield (engineering); Solvent; Ionic bonding; Liquid crystal; Selectivity; Materials science; Phase (matter); Benzene; Crystal (programming language); Chemistry; Organic chemistry; Photochemistry; Ion; Catalysis; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001491749,0.0002612798,0.0002657077,0.0000326211,0.0001954296,0.00003101147,0.000320612,0.0002113797,0.00034135],"category_scores_gemma":[0.0004908328,0.0002001501,0.000181532,0.0002628754,0.0001051318,0.00004634062,0.00006856016,0.0001643855,0.00003612174],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002862342,"about_ca_system_score_gemma":0.0001482973,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001643835,"about_ca_topic_score_gemma":0.000001121167,"domain_scores_codex":[0.9982905,0.00001145517,0.0004061293,0.0005039073,0.0002243529,0.0005636397],"domain_scores_gemma":[0.9987786,0.0001601193,0.0001033366,0.0005532223,0.0002237206,0.0001810029],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009220174,0.00009455117,5.585373e-7,0.0001092374,0.00007413774,0.000002169009,0.00007044258,0.0002972178,0.9951585,0.0003772938,0.003416091,0.0003075961],"study_design_scores_gemma":[0.0008030764,0.00008380327,0.00000130637,0.0001300896,0.00005224913,0.00002127379,0.00005222833,0.003735043,0.9242213,0.00005947142,0.07052124,0.0003189779],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8441958,0.001036677,0.1389424,0.009989613,0.0002552217,0.001307461,0.0001494741,0.0009147997,0.003208591],"genre_scores_gemma":[0.99294,0.00004947883,0.00097802,0.0001087663,0.0003626796,0.0008510568,0.00004561535,0.00007896508,0.004585392],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1487442,"threshold_uncertainty_score":0.8161883,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009734496514743904,"score_gpt":0.2358959994206472,"score_spread":0.2261615029059033,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}