{"id":"W2473276562","doi":"10.1039/c6cc04818h","title":"Anion recognition by a bidentate chalcogen bond donor","year":2016,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":171,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Chalcogen; Cooperativity; Denticity; Chemistry; Ion; Crystallography; Non-covalent interactions; Chelation; Group (periodic table); Molecule; Crystal structure; Hydrogen bond; Inorganic chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004765074,0.0001091071,0.00009470458,0.00003897675,0.0001361592,0.00002778764,0.0005043648,0.00009924176,0.0005545274],"category_scores_gemma":[0.00009358941,0.00009145292,0.0001268767,0.000120662,0.0001638748,0.0001246746,0.0001957417,0.000165318,0.0001299776],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006030595,"about_ca_system_score_gemma":0.00001453207,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004038122,"about_ca_topic_score_gemma":0.00001738702,"domain_scores_codex":[0.9993251,0.00001839301,0.0002118903,0.0001870775,0.0000909212,0.000166592],"domain_scores_gemma":[0.9985387,0.000177952,0.00008030602,0.001030707,0.00007630084,0.00009601716],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000010641,0.0001355421,0.00007325113,0.000007146765,0.00003281495,4.052916e-7,0.00004054784,6.655257e-9,0.9765525,0.0001705219,0.009203976,0.01377258],"study_design_scores_gemma":[0.0003467096,0.000005024253,0.000008930724,0.00006875239,0.00003167771,0.00001555523,0.00007440735,0.000006008926,0.7890968,0.001558248,0.2086402,0.0001476558],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8797863,0.001419726,0.002010499,0.008445876,0.00008138736,0.0001656859,0.001046126,0.0004340211,0.1066104],"genre_scores_gemma":[0.9965013,0.0007010322,0.001011736,0.000144909,0.00003498467,0.0001223588,0.0007205508,0.00002040898,0.0007427016],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1994362,"threshold_uncertainty_score":0.6071687,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02973300885103186,"score_gpt":0.2744808672708948,"score_spread":0.244747858419863,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}