{"id":"W2476643335","doi":"10.1139/cjc-2016-0230","title":"Chemical repair of protein carbon-centred radicals: long-distance dynamic factors","year":2016,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Thompson Rivers University","funders":"","keywords":"Chemistry; Radical; Intermolecular force; Reaction rate constant; Solvent; Thiol; Leucine; Chemical stability; Amino acid; Computational chemistry; Kinetics; Organic chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003572508,0.0004085715,0.0004214815,0.0003018363,0.0004463113,0.000324516,0.000524976,0.0003316958,0.002598656],"category_scores_gemma":[0.0007740681,0.0001856703,0.0003177395,0.0002974396,0.0006491598,0.0009089131,0.0003581533,0.0003826201,0.0002128798],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006364681,"about_ca_system_score_gemma":0.0004833254,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001404844,"about_ca_topic_score_gemma":0.001384834,"domain_scores_codex":[0.9999011,0.00001377429,0.000004140531,0.00002034786,0.00003150099,0.00002913182],"domain_scores_gemma":[0.9996285,0.0002047629,0.00005614395,0.00003336032,0.00004974761,0.00002749584],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006120475,0.0003520675,0.009733246,0.001180337,0.0001481838,0.001411903,0.0008015578,0.533269,0.3579839,0.05828517,0.000594306,0.03562817],"study_design_scores_gemma":[0.0001025575,0.0007265212,0.01320776,0.00005478568,0.0001234441,0.0006562921,0.0005699961,0.7551346,0.2016167,0.02377892,0.003890814,0.0001375893],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9746635,0.001847403,0.01967949,0.0001460104,0.00003258625,0.00003628094,0.00008690356,0.00005794853,0.003449844],"genre_scores_gemma":[0.9975622,0.000507492,0.001085522,0.00001283127,0.000005329641,0.00001953358,0.00005225343,0.0000118697,0.0007428693],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002598656,"threshold_uncertainty_score":0.008693337,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00826708582426281,"score_gpt":0.1969920484642484,"score_spread":0.1887249626399856,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}