{"id":"W2478279306","doi":"10.1016/j.polymer.2016.07.067","title":"Functional group tolerance of AOTEMPO-mediated peroxide cure chemistry","year":2016,"lang":"en","type":"article","venue":"Polymer","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"","keywords":"Polybutadiene; Polymer chemistry; Allylic rearrangement; Linear low-density polyethylene; Peroxide; Acrylate; Monomer; Polyethylene; Ethylene; Polymer; Diene; Methyl acrylate; Materials science; Vinyl acetate; Chemistry; Natural rubber; Organic chemistry; Copolymer; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002728012,0.0003588442,0.0001039191,0.0002025205,0.0001419991,0.0002225105,0.0002347893,0.0002932333,0.002949343],"category_scores_gemma":[0.0004247516,0.0001741709,0.0001206246,0.0001384834,0.0001819732,0.0004162331,0.0001912124,0.0004398467,0.0003840383],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001484684,"about_ca_system_score_gemma":0.0001423811,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001927513,"about_ca_topic_score_gemma":0.0003419308,"domain_scores_codex":[0.9998357,0.00001876211,0.000009842308,0.00004304128,0.00004945572,0.00004308959],"domain_scores_gemma":[0.9998208,0.00004212628,0.00005552144,0.00002378504,0.00004364586,0.00001412467],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006755323,0.00001295829,0.0001602541,0.00003509743,0.000002416497,0.00002819607,0.00002571655,0.00009709944,0.9965839,0.0002632343,0.00003338332,0.002690172],"study_design_scores_gemma":[0.000002094776,0.00007131046,0.0005477881,0.000001909718,0.000003267929,0.00002627371,0.000005728129,0.0003045223,0.9983308,0.00002299785,0.0006813505,0.000001999431],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9829947,0.0003503506,0.01208124,0.00004706623,0.00002527068,0.00004309877,0.0001603303,0.0001225907,0.004175411],"genre_scores_gemma":[0.9944172,0.0001868521,0.003177683,0.00002104445,0.000005353017,0.00002509278,0.0001437381,0.00003399991,0.001989104],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002949343,"threshold_uncertainty_score":0.009866595,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008600488122663386,"score_gpt":0.1986939212529401,"score_spread":0.1900934331302767,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}