{"id":"W2479303790","doi":"10.1039/c6sc01810f","title":"Exploring template-bound dinuclear copper porphyrin nanorings by EPR spectroscopy","year":2016,"lang":"en","type":"article","venue":"Chemical Science","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Sleep & Circadian Network","funders":"Engineering and Physical Sciences Research Council; University of Oxford","keywords":"Electron paramagnetic resonance; Porphyrin; Copper; Electron paramagnetic resonance spectroscopy; Spectroscopy; Crystallography; Metal; Ligand (biochemistry); Chemistry; Materials science; Photochemistry; Nuclear magnetic resonance; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0005243286,0.0002380709,0.0002251122,0.00004178906,0.0002645243,0.0001870283,0.001145994,0.00006732931,0.001546348],"category_scores_gemma":[0.0002460012,0.0001646146,0.00006477012,0.0004312322,0.001325253,0.001051962,0.0003912147,0.0001288908,0.001079515],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002720639,"about_ca_system_score_gemma":0.0001141399,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003813104,"about_ca_topic_score_gemma":2.526458e-7,"domain_scores_codex":[0.9972478,0.0000115526,0.0002922355,0.000852751,0.000691228,0.0009044796],"domain_scores_gemma":[0.9987437,0.00009046884,0.0001033235,0.0005168761,0.00007588771,0.0004698166],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001949127,0.00003862083,0.0005164595,0.00001099807,0.000001189766,0.000007587707,0.0000549855,1.008297e-7,0.994798,0.0002188197,0.004025484,0.0003082465],"study_design_scores_gemma":[0.0002909982,0.00002505087,0.0002354184,0.00006666437,0.000003597456,0.00003671427,0.00002122064,0.000002591072,0.9922161,0.0003929531,0.006406902,0.0003018011],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.987986,0.00004310361,0.00006511422,0.0004738829,0.000397612,0.00007608203,0.00002632366,0.0001805317,0.01075133],"genre_scores_gemma":[0.9977151,0.00003128413,0.001143106,0.0001098137,0.0001888206,0.00002531374,0.000001727289,0.00002243898,0.0007623524],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009988976,"threshold_uncertainty_score":0.9996983,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04650296342936665,"score_gpt":0.2549374520517701,"score_spread":0.2084344886224034,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}