{"id":"W2488830268","doi":"10.1039/c6gc01394e","title":"Hydrogen peroxide/dimethyl carbonate: a green system for epoxidation of N-alkylimines and N-sulfonylimines. One-pot synthesis of N-alkyloxaziridines from N-alkylamines and (hetero)aromatic aldehydes","year":2016,"lang":"en","type":"article","venue":"Green Chemistry","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Ministère de l'Enseignement Supérieur et de la Recherche; Natural Sciences and Engineering Research Council of Canada; Ministère de l'Enseignement Supérieur et de la Recherche Scientifique; Centre in Green Chemistry and Catalysis","keywords":"Dimethyl carbonate; Hydrogen peroxide; Chemistry; Carbonate; Green chemistry; Environmentally friendly; Organic chemistry; Hydrogen; Catalysis; Reaction mechanism","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002505757,0.0004385622,0.000960827,0.0001388919,0.00004731664,0.00001842515,0.0003205396,0.0003113695,0.00003668674],"category_scores_gemma":[0.0008034816,0.0003758573,0.0002099898,0.0002692071,0.0002818644,0.0002017036,0.000191223,0.00007428312,0.000001487035],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008789687,"about_ca_system_score_gemma":0.0000339948,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007914463,"about_ca_topic_score_gemma":0.0000323461,"domain_scores_codex":[0.9975499,0.00003156707,0.00102818,0.0006526597,0.0004035933,0.0003340801],"domain_scores_gemma":[0.9969087,0.001446536,0.0005796877,0.0006656127,0.0002313211,0.0001681388],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008999236,0.00004578964,0.003131175,0.002946846,0.0003800752,0.000002486791,0.0001709923,0.00001924187,0.9884526,0.00002301555,0.00001151908,0.004726285],"study_design_scores_gemma":[0.001033645,0.00002433233,0.0009409362,0.001011555,0.0005544118,0.00002338474,0.0002342746,0.004474863,0.9910381,0.0002255439,0.00003426158,0.0004046272],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960944,0.001093307,0.001274161,0.0002140909,0.00004556498,0.0003087339,0.0005984163,0.0001437954,0.0002275179],"genre_scores_gemma":[0.9973305,0.00009018515,0.001699654,0.000006931617,0.0001715648,0.0001713656,0.00008575443,0.00008507165,0.0003589487],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004455621,"threshold_uncertainty_score":0.9998693,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01332372557959005,"score_gpt":0.2101636574633744,"score_spread":0.1968399318837843,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}