{"id":"W2492265198","doi":"10.1139/cjc-2016-0282","title":"Structural features of the carbon–sulfur chemical bond: a semi-experimental perspective","year":2016,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"European Commission","keywords":"Chemistry; Sulfur; Molecule; Density functional theory; Carbon fibers; Computational chemistry; Work (physics); Field (mathematics); Biochemical engineering; Chemical physics; Thermodynamics; Algorithm; Organic chemistry; Computer science","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006336316,0.0001755647,0.0002687124,0.00002362178,0.00006328639,0.00002166465,0.0005705173,0.0001698711,0.0009002585],"category_scores_gemma":[0.0002292206,0.0001028895,0.000253115,0.00008257677,0.0004457208,0.00005878362,0.000030823,0.0003353193,6.244378e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004555604,"about_ca_system_score_gemma":0.001051129,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001129224,"about_ca_topic_score_gemma":0.0002195689,"domain_scores_codex":[0.9989005,0.000008162315,0.0003348019,0.0001589296,0.0002754799,0.0003220651],"domain_scores_gemma":[0.9987113,0.00004229994,0.0003062784,0.000270221,0.0001759213,0.0004939286],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000214181,0.00001112014,0.002345087,0.00003078861,0.00006211943,0.00005371146,0.000265073,6.039412e-7,0.9954812,0.00007187738,0.001465451,0.000191568],"study_design_scores_gemma":[0.0006457829,0.000008601421,0.0007128004,0.0002819116,0.00002157565,0.0006827817,0.0009116077,0.000002193483,0.9957066,0.0003030064,0.0005786436,0.0001444876],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9761394,0.001978486,2.820173e-7,0.000990333,0.0001266708,0.00001779007,0.0000711708,0.000004713562,0.02067118],"genre_scores_gemma":[0.9982793,0.000006480686,0.00002493634,0.00004607301,0.0004646021,8.766746e-7,6.721666e-7,0.00002015974,0.001156862],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02213996,"threshold_uncertainty_score":0.98572,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005705410753745042,"score_gpt":0.2103452584258544,"score_spread":0.2046398476721094,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}