{"id":"W2495966056","doi":"10.1007/s10847-011-9997-3","title":"Synthesis of the macrotricyclic ligands 8,18 dioxa-1,5,11,15-tetraaza-[13.5.2.25,11]-eicosane (L1) and 7,16 dioxa-1,4,10,13-tetraaza-[11.5.3.34,10]-octadecane (L2). Crystal structures of the copper(II) complexes, [Cu(L1)](ClO4)2 and [Cu(L2)](ClO4)2·CH3NO2","year":2011,"lang":"en","type":"article","venue":"Journal of Inclusion Phenomena and Macrocyclic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Victoria; Health Canada","funders":"","keywords":"Chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00102767,0.0008634311,0.002018921,0.0002300466,0.001158206,0.00008465634,0.001051782,0.000413903,0.001621694],"category_scores_gemma":[0.0008313092,0.0005046761,0.0006033887,0.0005404631,0.001418455,0.0002638909,0.002768473,0.0007874061,0.000001079199],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001960456,"about_ca_system_score_gemma":0.000289022,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005149957,"about_ca_topic_score_gemma":0.0002074487,"domain_scores_codex":[0.9948389,0.0002253658,0.002120298,0.0006995644,0.001370447,0.0007454373],"domain_scores_gemma":[0.9953624,0.0005922752,0.001924187,0.001053575,0.0004484837,0.0006190838],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001608755,0.0005830952,0.01948043,0.001937006,0.000485782,0.0000314737,0.00228042,0.000003415877,0.9646295,0.0000849777,0.003607442,0.005267751],"study_design_scores_gemma":[0.003755574,0.0005407765,0.05762971,0.001832037,0.001199239,0.002100595,0.002172357,0.00009031804,0.9128937,0.001462945,0.01557042,0.0007524],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9809375,0.01197578,0.000009580152,0.001018862,0.0002538624,0.0005484983,0.0001899174,0.00002918702,0.00503684],"genre_scores_gemma":[0.9941595,0.002254498,0.0002821501,0.0002867622,0.0004729455,0.00001609817,0.00001046628,0.00009385934,0.002423742],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05173583,"threshold_uncertainty_score":0.9997405,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02362183686319545,"score_gpt":0.2410038260940766,"score_spread":0.2173819892308811,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}