{"id":"W2498723959","doi":"10.1021/bk-2006-0928.ch033","title":"Luminescence Properties of Phosphine—Isocyanide Cu(I)- and Ag(I)-Containing Oligomers in the Solid State","year":2006,"lang":"en","type":"book-chapter","venue":"ACS symposium series","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada; Centre National de la Recherche Scientifique","keywords":"Luminescence; Phosphine; Polymer; Solid-state; Emission spectrum; Photochemistry; Exciton; Chemistry; Spectral line; Materials science; Analytical Chemistry (journal); Physical chemistry; Organic chemistry; Physics; Condensed matter physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001387845,0.0001855008,0.0001550066,0.0001545915,0.0001264948,0.0003631825,0.0002137163,0.0002218976,0.001165376],"category_scores_gemma":[0.0002917289,0.0001213853,0.00008281875,0.0002149683,0.0002315292,0.0001989975,0.0001573094,0.0002621858,0.0001985826],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003010199,"about_ca_system_score_gemma":0.0001239815,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005640034,"about_ca_topic_score_gemma":0.0005431204,"domain_scores_codex":[0.999889,0.00002745248,0.000006374348,0.00003029811,0.00002325302,0.00002368462],"domain_scores_gemma":[0.9998931,0.00003015169,0.00002633059,0.000007527427,0.00002095014,0.00002194777],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001481003,0.000021332,0.0002524822,0.00005950564,0.000005876374,0.00003380366,0.00009311023,0.0003094185,0.996978,0.0002361122,0.00005153808,0.001810804],"study_design_scores_gemma":[0.00001118804,0.0002902653,0.00261752,0.00001164414,0.00001234104,0.0000665741,0.00005268972,0.002332174,0.9933193,0.0000586458,0.001217824,0.000009859927],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980447,0.0003226721,0.0006501836,0.00001527634,0.000003484504,0.000003227721,0.00007359462,0.00003363465,0.0008533183],"genre_scores_gemma":[0.9977525,0.0001835804,0.0006804148,0.00001026724,0.000001725812,0.000006751873,0.0001566592,0.00001367516,0.001194293],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001165376,"threshold_uncertainty_score":0.003898621,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0161784008876898,"score_gpt":0.2197224772292142,"score_spread":0.2035440763415244,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}