{"id":"W2502340815","doi":"10.1002/cctc.201600738","title":"Catalyst Decomposition during Olefin Metathesis Yields Isomerization‐Active Ruthenium Nanoparticles","year":2016,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":72,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Isomerization; IMes; Ruthenium; Catalysis; Metathesis; Chemistry; Decomposition; Medicinal chemistry; Olefin fiber; Olefin metathesis; Salt metathesis reaction; Organic chemistry; Photochemistry; Carbene; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001772317,0.0003299681,0.0003627893,0.00004538443,0.0001575642,0.00004050588,0.0003903151,0.0002327892,0.003476669],"category_scores_gemma":[0.0004735764,0.0002675567,0.0001691387,0.0002352802,0.0001566314,0.0002051628,0.0001422677,0.0001415438,0.0002374421],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002953889,"about_ca_system_score_gemma":0.00006965657,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001569468,"about_ca_topic_score_gemma":0.000001960311,"domain_scores_codex":[0.9981515,0.00003143214,0.0004301982,0.0006038914,0.0003081272,0.0004747857],"domain_scores_gemma":[0.9982779,0.000414525,0.000217773,0.000789736,0.00009610209,0.0002039373],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006274447,0.0001144701,0.0004092126,0.00009540974,0.0001079001,0.000006991343,0.0005132515,3.037616e-7,0.9878668,0.00002766646,0.00005528484,0.01073992],"study_design_scores_gemma":[0.0007802872,0.000005048767,0.0003688161,0.0001210822,0.0001162604,0.00005930515,0.0003843829,0.000007352923,0.9968865,0.0004243176,0.0004509458,0.0003957266],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9911565,0.0001068652,0.0006868695,0.001132481,0.00008532072,0.00005989719,0.00005505698,0.0003058966,0.006411122],"genre_scores_gemma":[0.9933966,0.00003767721,0.00323016,0.00003198783,0.0002784047,0.00006361421,0.00002453887,0.00007895783,0.002858108],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0103442,"threshold_uncertainty_score":0.9999776,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01260657614380946,"score_gpt":0.2562980234623854,"score_spread":0.2436914473185759,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}