{"id":"W2504788041","doi":"10.1149/2.f02072if","title":"The Chalkboard: An Electroanalytical Approach for Investigating the Reaction Pathway of Molecules at Surfaces","year":2007,"lang":"en","type":"article","venue":"The Electrochemical Society Interface","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Electrochemistry; Kinetics; Chemical reaction; Chemical kinetics; Chemical energy; Molecule; Chemistry; Chemical thermodynamics; Reaction mechanism; Chemical physics; Electric energy; Electricity; Nanotechnology; Electrode; Computational chemistry; Thermodynamics; Materials science; Physical chemistry; Organic chemistry; Physics; Catalysis; Non-equilibrium thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003784133,0.0005771164,0.001042675,0.001562782,0.0010015,0.001953668,0.001777733,0.00158831,0.002575798],"category_scores_gemma":[0.0005199772,0.0003703691,0.0003803815,0.001065486,0.002845024,0.002823091,0.001154956,0.002188497,0.001042007],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006740906,"about_ca_system_score_gemma":0.0006649677,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005704062,"about_ca_topic_score_gemma":0.0006378082,"domain_scores_codex":[0.9996207,0.00005600425,0.00001135379,0.00008194456,0.0001850418,0.00004497323],"domain_scores_gemma":[0.999866,0.00005394036,0.000008525623,0.00002965655,0.00002767333,0.00001412647],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004379536,0.0001103786,0.0009234076,0.001373827,0.00007426251,0.0009568289,0.0007074676,0.004726269,0.4228653,0.4527005,0.007810073,0.1073136],"study_design_scores_gemma":[0.0000801319,0.0004246613,0.001336964,0.0002152428,0.00005296664,0.001829994,0.0006889171,0.07619621,0.4365752,0.3465839,0.1358698,0.0001460942],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.1189594,0.04641477,0.7616411,0.004705713,0.002474375,0.0004870099,0.0007066369,0.001839298,0.06277172],"genre_scores_gemma":[0.7426651,0.03075703,0.1760046,0.001979061,0.0004985681,0.0004381683,0.0003693609,0.0003326356,0.04695566],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.002575798,"threshold_uncertainty_score":0.008616865,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0140817656338269,"score_gpt":0.2653818714270743,"score_spread":0.2513001057932474,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}