{"id":"W2506962049","doi":"10.1039/c6sc02422j","title":"Photocatalyst size controls electron and energy transfer: selectable E/Z isomer synthesis via C–F alkenylation","year":2016,"lang":"en","type":"article","venue":"Chemical Science","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":171,"is_retracted":false,"has_abstract":true,"ca_institutions":"Stillwater (Canada)","funders":"National Institute of General Medical Sciences; Oklahoma Center for the Advancement of Science and Technology; Oklahoma State University; National Institutes of Health; National Science Foundation","keywords":"Photocatalysis; Energy transfer; Electron transfer; Electron; Chemistry; Photochemistry; Combinatorial chemistry; Medicinal chemistry; Materials science; Physics; Organic chemistry; Chemical physics; Catalysis; Nuclear physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001717539,0.0003423359,0.0001502012,0.0001113157,0.00007520186,0.0002329474,0.0002799744,0.0002429496,0.001434154],"category_scores_gemma":[0.0002371116,0.000122019,0.0001446075,0.00009760728,0.0001671629,0.0003818095,0.0002239709,0.0003139967,0.000226227],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000290201,"about_ca_system_score_gemma":0.000140634,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005779096,"about_ca_topic_score_gemma":0.00136762,"domain_scores_codex":[0.9998988,0.0000104958,0.00000725754,0.00003343719,0.00002243253,0.0000276245],"domain_scores_gemma":[0.9999267,0.00002645623,0.00001712901,0.000009758427,0.0000109725,0.000008953829],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009092859,0.00002257659,0.00006554521,0.00002887505,0.000004451683,0.00002471824,0.00001513685,0.0002551296,0.9954947,0.0002995864,0.00005030652,0.003647914],"study_design_scores_gemma":[0.000005765725,0.00004573589,0.0001934061,7.634496e-7,0.000003409433,0.00001416202,0.000003977495,0.0009260309,0.9984468,0.0000208049,0.0003366232,0.000002528659],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9886882,0.0005990639,0.006579757,0.00007209436,0.00003143433,0.00002863602,0.00008083331,0.0001021255,0.003817871],"genre_scores_gemma":[0.9973099,0.0002152076,0.00130702,0.00001639483,0.000004404287,0.000009736771,0.00003806625,0.00001597402,0.001083288],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001434154,"threshold_uncertainty_score":0.004797697,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004226184961593063,"score_gpt":0.2077391189240468,"score_spread":0.2035129339624537,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}