{"id":"W2507627252","doi":"10.1021/acscatal.5b00237","title":"Palladium Nanoparticles Supported in the Nanospaces of Imidazolium-Based Bifunctional PMOs: The Role of Plugs in Selectivity Changeover in Aerobic Oxidation of Alcohols","year":2015,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":110,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Iran National Science Foundation","keywords":"Selectivity; Catalysis; Chemistry; Bifunctional; Diffuse reflectance infrared fourier transform; Palladium; Alcohol oxidation; Benzoic acid; Thermogravimetric analysis; X-ray photoelectron spectroscopy; Fourier transform infrared spectroscopy; Heterogeneous catalysis; Magic angle spinning; Chemical engineering; Nuclear chemistry; Organic chemistry; Photocatalysis; Nuclear magnetic resonance spectroscopy","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001222309,0.0004857226,0.000312034,0.0001894038,0.00009051875,0.0004062194,0.0003712208,0.0003160672,0.0003250012],"category_scores_gemma":[0.0001878705,0.0002404174,0.0002018138,0.000139216,0.0002187416,0.0003683836,0.0002962256,0.0003077419,0.000231576],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002560919,"about_ca_system_score_gemma":0.0001054557,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003403716,"about_ca_topic_score_gemma":0.0005908647,"domain_scores_codex":[0.9998713,0.00001384219,0.0000125746,0.00004004967,0.00003244664,0.00002994694],"domain_scores_gemma":[0.9999148,0.00001538135,0.00002672313,0.000009383842,0.00001160653,0.00002222019],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003737453,0.00001050656,0.00007109106,0.00002774326,0.000003735795,0.00002753469,0.000008521426,0.00005441376,0.9988954,0.00003389067,0.000009011868,0.0008208292],"study_design_scores_gemma":[0.000004785963,0.00007823243,0.0004343316,0.000001783016,0.000007488802,0.00004280186,0.000009026331,0.0007046978,0.9983587,0.00001069547,0.0003441984,0.000003339061],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947648,0.0006001797,0.003920484,0.00002904177,0.00001961032,0.0000134172,0.00008895295,0.0001139239,0.0004495961],"genre_scores_gemma":[0.9964859,0.0003305506,0.002433013,0.00001289312,0.000006918809,0.000009263688,0.000100322,0.00001756327,0.0006036164],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0004857226,"threshold_uncertainty_score":0.001858056,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01983357260267053,"score_gpt":0.2408005009095308,"score_spread":0.2209669283068602,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}