{"id":"W2508074551","doi":"10.1002/9781118839621.ch13","title":"Tight Bite Angle<i>N</i>,<i>O</i>‐Chelates. Amidates, Ureates and Beyond","year":2016,"lang":"en","type":"other","venue":"","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Protonolysis; Hydroamination; Ligand (biochemistry); Yttrium; Catalysis; Bite angle; Chelation; Chemistry; Polymerization; Zirconium; Polymer chemistry; Materials science; Denticity; Metal; Inorganic chemistry; Organic chemistry; Oxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001664282,0.0008096213,0.0002797742,0.0004362269,0.0003074665,0.0006729785,0.0005037567,0.0003265793,0.01177263],"category_scores_gemma":[0.0001317712,0.0001905612,0.0001409848,0.000352589,0.0003382086,0.0006867079,0.0008936841,0.0004438954,0.004523544],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006411273,"about_ca_system_score_gemma":0.0003620072,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001009291,"about_ca_topic_score_gemma":0.001926882,"domain_scores_codex":[0.9999021,0.000008432549,0.000005596371,0.00002966933,0.00003107594,0.00002306616],"domain_scores_gemma":[0.999964,0.000003122219,0.000009746924,0.000006751523,0.000006361927,0.00001001809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003493629,0.0001412919,0.000462615,0.001273628,0.00002802364,0.0005889868,0.0001973974,0.001820458,0.6628691,0.1314549,0.01531372,0.1855005],"study_design_scores_gemma":[0.00004055168,0.0002989981,0.0006793418,0.00005681613,0.00001941346,0.0006826872,0.00007374428,0.002283831,0.4773913,0.006281192,0.5121503,0.00004183418],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2897443,0.04753898,0.06105457,0.001204661,0.001085962,0.0002640187,0.001460741,0.002465345,0.5951815],"genre_scores_gemma":[0.7411146,0.02249335,0.02033865,0.000431682,0.000204526,0.000161697,0.0009172517,0.0003849795,0.2139532],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.01177263,"threshold_uncertainty_score":0.03938335,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005596683970722852,"score_gpt":0.2021612942232609,"score_spread":0.1965646102525381,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}