{"id":"W2508079888","doi":"10.1139/cjc-2016-0358","title":"Synthesis, structure, and first reactions of a new class of thiacyclophanes","year":2016,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Yield (engineering); Flash vacuum pyrolysis; Cyclophane; Sulfone; Chloride; Pyrolysis; Molecule; Conjugated system; Hydrocarbon; Organic chemistry; Polymer chemistry; Stereochemistry; Polymer","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009125042,0.0001180413,0.0003113262,0.00004645522,0.00004872548,0.00001482371,0.0002579147,0.000112537,0.002728762],"category_scores_gemma":[0.0006443899,0.00008180767,0.0001015663,0.00004782177,0.0001714886,0.00008324176,0.00001341421,0.0000967513,5.03621e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006637784,"about_ca_system_score_gemma":0.000812865,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001508707,"about_ca_topic_score_gemma":0.0008689418,"domain_scores_codex":[0.9991106,0.00000620456,0.0004847875,0.00009254713,0.0001458406,0.0001599781],"domain_scores_gemma":[0.9984945,0.0002877481,0.0004509061,0.0002337157,0.0001250277,0.0004081176],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003918048,0.00001133394,0.008275281,0.0005503197,0.0001546062,0.00001621506,0.0002674451,0.000002444716,0.9749384,0.00001594585,0.003764723,0.01196411],"study_design_scores_gemma":[0.0002616128,0.00001023105,0.0009099075,0.001080211,0.00004977188,0.0002870585,0.0002236876,0.000001852588,0.9694136,0.0007516375,0.02690369,0.0001067512],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9895968,0.001369899,0.000005194476,0.001057702,0.00005327008,0.00001166448,0.00006143798,0.000002894707,0.007841078],"genre_scores_gemma":[0.9983562,0.0001289826,0.0002416932,0.000008242088,0.0001629294,4.713112e-7,4.463009e-7,0.00001343786,0.001087545],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02313897,"threshold_uncertainty_score":0.9981829,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01168218643233583,"score_gpt":0.1920506687667533,"score_spread":0.1803684823344175,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}