{"id":"W2509231898","doi":"10.1139/v05-089","title":"Synthesis and reactivity of the macrobicyclic complexes (1,5,8,12-tetraaza-17-oxabicyclo[10.5.2]nonadecane)cobalt(III) perchlorate ([Co(L<sub>1</sub>)(ClO<sub>4</sub>)](ClO<sub>4</sub>)<sub>2</sub>), [(chloro(1,4,8,11-tetraaza-17-oxabicyclo[9.5.3]nonadecane)cobalt(III) perchlorate ([Co(L<sub>2</sub>)(Cl)](ClO<sub>4</sub>)<sub>2</sub>), (4,8-dimethyl-1,4,8,11-tetraaza-17-oxabicyclo[9.5.3]nonadecane)cobalt(III) perchlorate ([Co(L<sub>3</sub>)(ClO<sub>4</sub>)](ClO<sub>4</sub>)<sub>2</sub>), and (5,8-dimethyl-1,5,8,12-tetraaza-17-oxabicyclo[10.5.2]nonadecane)cobalt(III) perchlorate ([Co(L<sub>4</sub>)(ClO<sub>4</sub>)](ClO<sub>4</sub>)<sub>2</sub>) Crystal structure of the L<sub>2</sub> complex","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Perchlorate; Reactivity (psychology); Medicinal chemistry; Cobalt; Ligand (biochemistry); Metal; Ether; Amine gas treating; Molecule; Chloride; Metal ions in aqueous solution; Coordination complex; Inorganic chemistry; Ion; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007585368,0.0001669327,0.0001797178,0.0001039212,0.0001647389,0.0002723298,0.000212946,0.0001460221,0.001663341],"category_scores_gemma":[0.0001472755,0.0001195022,0.00009025457,0.0001312446,0.0001126974,0.000108965,0.0001626934,0.0001941957,0.0004510319],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004161557,"about_ca_system_score_gemma":0.0003695708,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002029792,"about_ca_topic_score_gemma":0.003951828,"domain_scores_codex":[0.9999045,0.000009680112,0.000005811156,0.00002443212,0.00002801808,0.00002750419],"domain_scores_gemma":[0.9999323,0.00000621847,0.0000127471,0.000006354473,0.00001807847,0.00002421535],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003066991,0.00002118803,0.0003763799,0.0001844405,0.00001363997,0.00005963407,0.00006222217,0.0005483942,0.9896184,0.0006421275,0.0003500515,0.007816797],"study_design_scores_gemma":[0.00001534075,0.0001872909,0.001262141,0.000007034903,0.00001155626,0.0001253979,0.00002733468,0.0004303282,0.986223,0.000056741,0.01164477,0.000009079209],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9777755,0.005763145,0.004160823,0.0001335296,0.0000619573,0.00008615746,0.0006170972,0.0001162626,0.01128541],"genre_scores_gemma":[0.9833395,0.001750684,0.003724326,0.00006789523,0.000009371566,0.0000601538,0.0006461437,0.00004046916,0.01036146],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002029792,"threshold_uncertainty_score":0.005564392,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02187216028917867,"score_gpt":0.2390886767168689,"score_spread":0.2172165164276902,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}