{"id":"W2509231898","doi":"10.1139/v05-089","title":"Synthesis and reactivity of the macrobicyclic complexes (1,5,8,12-tetraaza-17-oxabicyclo[10.5.2]nonadecane)cobalt(III) perchlorate ([Co(L<sub>1</sub>)(ClO<sub>4</sub>)](ClO<sub>4</sub>)<sub>2</sub>), [(chloro(1,4,8,11-tetraaza-17-oxabicyclo[9.5.3]nonadecane)cobalt(III) perchlorate ([Co(L<sub>2</sub>)(Cl)](ClO<sub>4</sub>)<sub>2</sub>), (4,8-dimethyl-1,4,8,11-tetraaza-17-oxabicyclo[9.5.3]nonadecane)cobalt(III) perchlorate ([Co(L<sub>3</sub>)(ClO<sub>4</sub>)](ClO<sub>4</sub>)<sub>2</sub>), and (5,8-dimethyl-1,5,8,12-tetraaza-17-oxabicyclo[10.5.2]nonadecane)cobalt(III) perchlorate ([Co(L<sub>4</sub>)(ClO<sub>4</sub>)](ClO<sub>4</sub>)<sub>2</sub>) Crystal structure of the L<sub>2</sub> complex","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Perchlorate; Reactivity (psychology); Medicinal chemistry; Cobalt; Ligand (biochemistry); Metal; Ether; Amine gas treating; Molecule; Chloride; Metal ions in aqueous solution; Coordination complex; Inorganic chemistry; Ion; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"category_scores_codex":[0.02844582,0.03841218,0.04052525,0.01849915,0.02074981,0.01150014,0.02839658,0.02469461,0.001036824],"category_scores_gemma":[0.01479505,0.03949229,0.02283416,0.02834865,0.03194093,0.01802076,0.0110267,0.04470661,0.002878845],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.02738922,"about_ca_system_score_gemma":0.03683051,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003761556,"about_ca_topic_score_gemma":0.06097225,"domain_scores_codex":[0.851189,0.01809988,0.03712324,0.02955586,0.02813155,0.03590051],"domain_scores_gemma":[0.8768736,0.01696003,0.03186927,0.02610153,0.01636699,0.03182862],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01845162,0.008203704,0.003783556,0.01169244,0.01477688,0.007769813,0.006693044,0.005448179,0.8047928,0.000446295,0.05615555,0.06178617],"study_design_scores_gemma":[0.03336206,0.005555439,0.02108725,0.01503583,0.01654599,0.01879085,0.007529806,0.003452406,0.8303077,0.003456545,0.01238854,0.03248762],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8935829,0.02114767,0.0008561513,0.009162513,0.0106626,0.02516292,0.03121486,0.005105313,0.003105025],"genre_scores_gemma":[0.8981065,0.04954005,0.0008675685,0.008371932,0.01549205,0.00514206,0.01119032,0.01101654,0.0002729728],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05721069,"threshold_uncertainty_score":0.9998764,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02187216028917867,"score_gpt":0.2390886767168689,"score_spread":0.2172165164276902,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}