{"id":"W2510481862","doi":"10.1021/acsmacrolett.5b00676","title":"Influence of Confinement on the Chain Conformation of Cyclic Poly(<i>N</i>-isopropylacrylamide)","year":2015,"lang":"fr","type":"article","venue":"ACS Macro Letters","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"NanoLund, Lunds Universitet; National Institute of Metrology, China; Deutsche Forschungsgemeinschaft","keywords":"Radius of gyration; Gyration; Materials science; Polymer; RADIUS; Hydrodynamic radius; Substrate (aquarium); Ring (chemistry); Scattering; Polymer chemistry; Macromolecule; Poly(N-isopropylacrylamide); Chain (unit); Chemical physics; Molecular physics; Crystallography; Composite material; Optics; Chemistry; Physics; Copolymer; Geometry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005887934,0.000229755,0.0002464628,0.00005582439,0.00006919187,0.00001440193,0.0004730491,0.0001586906,0.00002725269],"category_scores_gemma":[0.0002660284,0.0001867607,0.00009739854,0.0001538717,0.0006376755,0.00001303894,0.0001426435,0.0001436441,0.0000621189],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005154642,"about_ca_system_score_gemma":0.0001351215,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005958941,"about_ca_topic_score_gemma":0.00002964105,"domain_scores_codex":[0.998337,0.0001707322,0.0005973788,0.0002679173,0.0003127596,0.00031421],"domain_scores_gemma":[0.9984219,0.00005408434,0.0004488916,0.0007827578,0.0001973547,0.00009499163],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000875476,0.0001159823,0.0004193783,0.00009863997,0.0001277695,9.198871e-7,0.0008164451,0.002185555,0.9802461,0.001825401,0.007993904,0.006082406],"study_design_scores_gemma":[0.0004143181,0.0002178419,0.0007938474,0.00009165876,0.00005038403,0.000007155992,0.0002582255,0.000158772,0.9202141,0.00006815521,0.07753257,0.0001929583],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9599,0.002585631,0.0005132331,0.03516325,0.0001116511,0.0005824054,0.00008206089,0.000008828192,0.001053002],"genre_scores_gemma":[0.9920273,0.00031992,0.0001632154,0.006871582,0.0001087064,0.00009510632,0.00004627141,0.00002518581,0.0003426706],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06953866,"threshold_uncertainty_score":0.7615882,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01639932388670992,"score_gpt":0.2339904908955509,"score_spread":0.217591167008841,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}