{"id":"W2510684471","doi":"10.1021/acs.organomet.5b00537","title":"Unsymmetrical Saturated Ketones Resulting from Activations of Hydrocarbon C(sp<sup>3</sup>)–H and C(sp<sup>2</sup>)–H Bonds Effected by Cp*W(NO)(H)(η<sup>3</sup>-allyl) Complexes","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid; Dow Chemical Company","keywords":"Chemistry; Ligand (biochemistry); Mesitylene; Hydride; Medicinal chemistry; Benzene; Adduct; Ketone; Alkyl; Group 2 organometallic chemistry; Alkene; Hydrocarbon; Double bond; Stereochemistry; Metal; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001485322,0.0005649503,0.0001822105,0.0001540123,0.0001333273,0.0001603711,0.0002482008,0.0001690562,0.002293271],"category_scores_gemma":[0.000165098,0.0001753352,0.0001301661,0.0001834853,0.0002511243,0.0002679019,0.0003286867,0.000356236,0.0005396205],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002075122,"about_ca_system_score_gemma":0.0002826996,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004849616,"about_ca_topic_score_gemma":0.001652694,"domain_scores_codex":[0.9998621,0.00001550936,0.000007749872,0.00002038274,0.00003353771,0.00006078376],"domain_scores_gemma":[0.9998971,0.00001320455,0.00002853127,0.00001488407,0.00001311553,0.00003319408],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000346634,0.00003502709,0.0002851376,0.0001851522,0.00002170058,0.0002290676,0.0001196484,0.0002960874,0.9940565,0.0007816253,0.0002663114,0.003377194],"study_design_scores_gemma":[0.00001054959,0.0001301945,0.0006976866,0.000003609523,0.000006788747,0.00008750461,0.00002368457,0.0002240868,0.9972493,0.00005220602,0.001508452,0.000005856945],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906952,0.0004426162,0.003200415,0.00004617717,0.00004561543,0.00002676503,0.0002802239,0.00009932843,0.005163693],"genre_scores_gemma":[0.9958133,0.0003433818,0.0009693839,0.00001982439,0.000004589494,0.00001516491,0.0002256585,0.00002327696,0.002585426],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002293271,"threshold_uncertainty_score":0.007671714,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01878692859953889,"score_gpt":0.2315448201546867,"score_spread":0.2127578915551478,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}