{"id":"W2510917377","doi":"10.1002/slct.201600670","title":"Synthesis, Structures and Conformational Studies of 1,2‐Dimethyl[2.10]metacyclophan‐1‐enes","year":2016,"lang":"en","type":"article","venue":"ChemistrySelect","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Engineering and Physical Sciences Research Council; Guizhou University; Royal Society","keywords":"Chemistry; Intramolecular force; Hydrogen bond; Substituent; Ene reaction; Cyclopentene; Coupling reaction; Medicinal chemistry; Stereochemistry; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008472011,0.0002479009,0.0001552488,0.0001334039,0.00007871431,0.0001213215,0.0001915595,0.0001782747,0.001041104],"category_scores_gemma":[0.0001340751,0.0001010204,0.0001039398,0.000142401,0.00007005591,0.0001336827,0.00009878693,0.0002197538,0.0002493961],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001635673,"about_ca_system_score_gemma":0.0001124131,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004799462,"about_ca_topic_score_gemma":0.0009286538,"domain_scores_codex":[0.9999431,0.00001060702,0.000004223448,0.00001157798,0.0000115476,0.00001899176],"domain_scores_gemma":[0.9999279,0.00001067886,0.00002010495,0.000007765673,0.00001228064,0.00002122053],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009668079,0.00001776353,0.00009645691,0.00006167399,0.000006365239,0.00009177267,0.00002212491,0.0004243681,0.9969786,0.0001210922,0.00002946849,0.002053639],"study_design_scores_gemma":[0.00001081502,0.0005203287,0.001683278,0.000005041203,0.00001133293,0.0001827468,0.00001702838,0.0003607685,0.9936408,0.00002434931,0.003535589,0.000007857028],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993163,0.002408415,0.001485153,0.00002260891,0.00001745901,0.00002649241,0.0003908346,0.00002318024,0.002462967],"genre_scores_gemma":[0.9929981,0.001317661,0.002764316,0.00002584391,0.000004879672,0.00001949851,0.000415682,0.00001089552,0.00244317],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001041104,"threshold_uncertainty_score":0.003482878,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02900257336006602,"score_gpt":0.2629414295695217,"score_spread":0.2339388562094556,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}