{"id":"W2511239946","doi":"10.1021/acs.jpcc.5b03038","title":"Direct Measurement of Surface Termination Groups and Their Connectivity in the 2D MXene V<sub>2</sub>CT<sub><i>x</i></sub> Using NMR Spectroscopy","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"MXene and MAX Phase Materials","field":"Materials Science","cited_by":226,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"National Research Council Canada; Social Sciences and Humanities Research Council of Canada; Natural Sciences and Engineering Research Council of Canada; Canada Excellence Research Chairs, Government of Canada; Canada Foundation for Innovation","keywords":"MXenes; Solid-state nuclear magnetic resonance; Hydroxide; Nuclear magnetic resonance spectroscopy; Materials science; Crystallography; Fluorine-19 NMR; Surface layer; Molecule; Chemistry; Layer (electronics); Inorganic chemistry; Nanotechnology; Nuclear magnetic resonance; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005498325,0.0003045935,0.0001055753,0.000147076,0.000166416,0.000231521,0.0001779585,0.0003251961,0.001035276],"category_scores_gemma":[0.0001947333,0.0001835258,0.0000917772,0.0001145144,0.0002348419,0.000318055,0.0002128388,0.0004138971,0.0001448896],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001659552,"about_ca_system_score_gemma":0.00008621604,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005249853,"about_ca_topic_score_gemma":0.0009247062,"domain_scores_codex":[0.9999461,0.000005137396,0.000002156185,0.0000188935,0.00001896805,0.000008694913],"domain_scores_gemma":[0.9999328,0.00001800044,0.00002349667,0.000004957676,0.00001086812,0.000009989084],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002835576,0.000004684297,0.0004045531,0.00002078663,0.000002733742,0.00003191224,0.00002577853,0.0001276923,0.9985296,0.0000936111,0.00001877631,0.0007115264],"study_design_scores_gemma":[0.000005789383,0.0001177705,0.005889659,0.000006820019,0.00001160383,0.0001088036,0.00007785011,0.001955567,0.9908192,0.00006858675,0.0009289216,0.000009478651],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965179,0.0002238119,0.00160602,0.0000216311,0.000005705678,0.00000729727,0.0001678355,0.00002661333,0.001423152],"genre_scores_gemma":[0.9963595,0.0003004968,0.002286386,0.00002252572,0.000003846445,0.00001869631,0.0002837443,0.000009690123,0.0007150134],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001035276,"threshold_uncertainty_score":0.003463328,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03253832776200873,"score_gpt":0.2633116600767955,"score_spread":0.2307733323147868,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}