{"id":"W2511574795","doi":"10.1039/c6ob01663d","title":"Racemic and enantioselective metal-catalyzed synthesis of SF<sub>5</sub>-containing diarylmethanols","year":2016,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies; Université Laval","keywords":"Enantioselective synthesis; Chemistry; Catalysis; Metal; Combinatorial chemistry; Organic chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001912864,0.000316496,0.0002034855,0.0001387323,0.000120129,0.0001615749,0.0004172108,0.0002443812,0.001477745],"category_scores_gemma":[0.0002269135,0.00009500663,0.0001469848,0.0001781118,0.000149126,0.0003668183,0.0001599293,0.0004035292,0.0005635402],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002904789,"about_ca_system_score_gemma":0.0002688597,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005012123,"about_ca_topic_score_gemma":0.001134419,"domain_scores_codex":[0.999926,0.000009781015,0.000009380573,0.00001495416,0.00001439717,0.00002544317],"domain_scores_gemma":[0.999944,0.00001172352,0.00001810335,0.00000724343,0.00001027482,0.000008654151],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001916977,0.00005658926,0.0002273032,0.0001856542,0.00001878022,0.000306651,0.0001041364,0.0008540952,0.9796791,0.002614374,0.0004371796,0.01532449],"study_design_scores_gemma":[0.00001129839,0.0001448572,0.0003003357,0.000005773778,0.000009981904,0.0001662567,0.00001757325,0.0004384538,0.993725,0.0001214538,0.005051152,0.000007944027],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9423842,0.004246483,0.03949067,0.0002653708,0.0001265285,0.0001177357,0.001243157,0.0002929688,0.0118329],"genre_scores_gemma":[0.9780005,0.002373783,0.01525418,0.00006522608,0.00001036732,0.00003452419,0.0006758046,0.00003513157,0.003550568],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001477745,"threshold_uncertainty_score":0.00494355,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02449071244838473,"score_gpt":0.3158816639424532,"score_spread":0.2913909514940685,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}